C₇₃H₁₁₁NOSi₂

Base Information

• Chemical Name: C₇₃H₁₁₁NOSi₂
• CAS No.: 1313995-10-6
• Molecular Formula: C₇₃H₁₁₁NOSi₂
• Molecular Weight: 1074.86
• Mol file: 1313995-10-6.mol

Synonyms:C₇₃H₁₁₁NOSi₂

Chemical Property of C₇₃H₁₁₁NOSi₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₇₃H₁₁₁NOSi₂

There total 9 articles about C₇₃H₁₁₁NOSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

C51H69I2NO (1313995-09-3) + tris-iso-propylsilyl acetylene (89343-06-6) → C73H111NOSi2 (1313995-10-6)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; Inert atmosphere;

DOI:10.1039/c1ob05441d

Reference yield:

3,5-diiodobenzoic acid (19094-48-5) → C73H111NOSi2 (1313995-10-6)

Guidance literature:

Multi-step reaction with 5 steps

1: benzotriazol-1-ol; dicyclohexyl-carbodiimide / tetrahydrofuran / Reflux

2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 20 °C / Inert atmosphere

3: water; potassium hydroxide / tetrahydrofuran; methanol / 0.25 h

4: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / Inert atmosphere

5: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; water; benzotriazol-1-ol; triethylamine; N-ethyl-N,N-diisopropylamine; dicyclohexyl-carbodiimide; potassium hydroxide; In tetrahydrofuran; methanol; 2: Castro-Stephen-Sonogashira coupling / 4: Castro-Stephen-Sonogashira coupling / 5: Castro-Stephen-Sonogashira coupling;

DOI:10.1039/c1ob05441d

Reference yield:

N-dodecyl-3,5-diiodo-benzamide (1313995-07-1) → C73H111NOSi2 (1313995-10-6)

Guidance literature:

Multi-step reaction with 4 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 20 °C / Inert atmosphere

2: water; potassium hydroxide / tetrahydrofuran; methanol / 0.25 h

3: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / Inert atmosphere

4: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; water; triethylamine; N-ethyl-N,N-diisopropylamine; potassium hydroxide; In tetrahydrofuran; methanol; 1: Castro-Stephen-Sonogashira coupling / 3: Castro-Stephen-Sonogashira coupling / 4: Castro-Stephen-Sonogashira coupling;

DOI:10.1039/c1ob05441d

upstream raw materials:

N-dodecyl-3,5-diiodo-benzamide

C₂₉H₄₇NOSi₂

C₂₃H₃₁NO

2,6-diiodo-4-octylaniline