N-2,6,8-nonatrienylpiperidine

Base Information

• Chemical Name: N-2,6,8-nonatrienylpiperidine
• CAS No.: 74067-07-5
• Molecular Formula: C₁₄H₂₃N
• Molecular Weight: 205.343
• Mol file: 74067-07-5.mol

Synonyms:N-2,6,8-nonatrienylpiperidine

Chemical Property of N-2,6,8-nonatrienylpiperidine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-2,6,8-nonatrienylpiperidine

There total 3 articles about N-2,6,8-nonatrienylpiperidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

1-piperidinomethanol (2494-10-2) + (E)-1,3,7-octatriene (26198-79-8) → piperidine (110-89-4) + di(N-piperidinyl)methane (880-09-1) + N-2,6,8-nonatrienylpiperidine (74067-07-5)

Guidance literature:

Ps(acac)2; triethylaluminum; triphenylphosphine; In toluene; for 6h; Heating;

DOI:10.1007/BF00961758

Reference yield:

1-piperidinomethanol (2494-10-2) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → (E)-1,3,7-octatriene (26198-79-8) + (E)-1-(octa-2,7-dien-1-yl)piperidine (67732-44-9) + 2,5-divinyltetrahydropyran (25724-33-8) + 4-ethenylcyclohexene (100-40-3) + N-2,6,8-nonatrienylpiperidine (74067-07-5) + 1,1'-piperidyl-3,8-nonadiene (74067-08-6)

Guidance literature:

palladium(II) acetylacetonate; triethylaluminum; triphenylphosphine; In toluene; at 120 ℃; for 10h; Product distribution; telomerization of butadiene with N-hydroxymethylamines (N-hydroxymethylpiperidine and N-hydroxymethyldiethylamine) in the presence of Pd catalyst, mixed telomerization of butadiene with formaldehyde and secondary amines (piperidine and diethylamine);

DOI:10.1007/BF00961758

Reference yield:

1-piperidinomethanol (2494-10-2) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → (E)-1-(octa-2,7-dien-1-yl)piperidine (67732-44-9) + 4-ethenylcyclohexene (100-40-3) + N-2,6,8-nonatrienylpiperidine (74067-07-5) + 1,1'-piperidyl-3,8-nonadiene (74067-08-6)

Guidance literature:

Ps(acac)2; triethylaluminum; triphenylphosphine; In toluene; at 120 ℃; for 10h; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1007/BF00961758

upstream raw materials:

1-piperidinomethanol

(E)-1,3,7-octatriene

buta-1,3-diene