benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside

Base Information

• Chemical Name: benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside
• CAS No.: 1192256-26-0
• Molecular Formula: C₂₂H₂₆O₅
• Molecular Weight: 370.445
• Mol file: 1192256-26-0.mol

Synonyms:benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside

Chemical Property of benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside

There total 1 articles about benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

5-hexenoic acid (1577-22-6) + benzyl 6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside (1192256-23-7) → benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside (1192256-26-0)

Guidance literature:

With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine; In acetonitrile; for 4h;

DOI:10.1016/j.tet.2009.07.088

Reference yield:

ethene (74-85-1) + benzyl 4-O-(hex-5-enoyl)-6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside (1192256-26-0) → C22H26O5

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; Reflux;

DOI:10.1016/j.tet.2009.07.088

upstream raw materials:

5-hexenoic acid

benzyl 6-O-propargyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside