dimethyl 2'-(5-hexynyl)homophthalate

Base Information

• Chemical Name: dimethyl 2'-(5-hexynyl)homophthalate
• CAS No.: 131353-33-8
• Molecular Formula: C₁₇H₂₀O₄
• Molecular Weight: 288.343
• Mol file: 131353-33-8.mol

Synonyms:dimethyl 2'-(5-hexynyl)homophthalate

Chemical Property of dimethyl 2'-(5-hexynyl)homophthalate

Chemical Property:

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Technology Process of dimethyl 2'-(5-hexynyl)homophthalate

There total 1 articles about dimethyl 2'-(5-hexynyl)homophthalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyl homophthalate (716-43-8) + 1-iodo-5-hexyne (2468-56-6) → dimethyl 2'-(5-hexynyl)homophthalate (131353-33-8)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; Yield given. Multistep reaction; 1) THF, hexane, -78 deg C, 30 min, 2) THF, -78 deg C to r.t.;

DOI:10.1021/jo00001a024

Reference yield: 95.0%

dimethyl 2'-(5-hexynyl)homophthalate (131353-33-8) → 2'-(5-hexynyl)homophthalic acid (131353-35-0)

Guidance literature:

With potassium hydroxide; In methanol; water; for 3h; Heating;

DOI:10.1021/jo00001a024

upstream raw materials:

dimethyl homophthalate

1-iodo-5-hexyne

Downstream raw materials:

2'-(5-hexynyl)homophthalic acid