[rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C₆H₅)2C₄H₄P(C₆H₅)2]

Base Information

• Chemical Name: [rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C₆H₅)2C₄H₄P(C₆H₅)2]
• CAS No.: 334698-24-7
• Molecular Formula: C₅₆H₄₅P₂Rh
• Molecular Weight: 882.826

Synonyms:[rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C₆H₅)2C₄H₄P(C₆H₅)2]

Chemical Property of [rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C₆H₅)2C₄H₄P(C₆H₅)2]

Chemical Property:

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Technology Process of [rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C₆H₅)2C₄H₄P(C₆H₅)2]

There total 2 articles about [rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C₆H₅)2C₄H₄P(C₆H₅)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate (334698-26-9) → [rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C6H5)2C4H4P(C6H5)2] (334698-24-7)

Guidance literature:

With potassium tert-butoxide; In tetrahydrofuran; Rh complex as suspn. mixed with potassium tert-butoxide in THF; pptd.(hexane), elem. anal.;

DOI:10.1039/b002906h

Reference yield:

bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(0) → [rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C6H5)2C4H4P(C6H5)2] (334698-24-7)

Guidance literature:

In not given; byproducts: H2; at 70°C for 15 min;

DOI:10.1039/b002906h

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + n-butyllithium (109-72-8,29786-93-4) + [rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C6H5)2C4H4P(C6H5)2] (334698-24-7) → [rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]][(C6H4)2C3H2CH2C4H9P(C6H5)2]rhodium(I-) Li(THF)4 (334698-32-7)

Guidance literature:

In tetrahydrofuran; hexane; metal complex in THF treated with Li reagent in hexane, stirred at room temp. for 5 min; crystd.(hexane);

DOI:10.1039/b002906h

upstream raw materials:

bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

Downstream raw materials:

[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]][(C₆H₄)2C₃H₂CH₂C₄H₉P(C₆H₅)2]rhodium(I-) Li(THF)4

bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I-) Li(THF)4

[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]][(C₆H₄)2C₃H₂CH₂C₆H₅P(C₆H₅)2]rhodium(I-) Li(THF)4

[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]][(C₆H₄)2C₃H₂CH₂CH₃P(C₆H₅)2]rhodium(I-) Li(THF)4

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