6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene

Base Information

• Chemical Name: 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene
• CAS No.: 129135-32-6
• Molecular Formula: C₃₂H₃₆N₄O₄S₂
• Molecular Weight: 604.794

Synonyms:6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene

Chemical Property of 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene

There total 5 articles about 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2,6-bis(chloromethyl)pyridine (3099-28-3) + N3-benzyl-N1,N5-ditosyl-3-aza-1,5-pentanediamine (112193-79-0) → 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1(15),11,13-triene (129135-32-6)

Guidance literature:

With potassium carbonate; In acetonitrile; for 11h; Reflux; Inert atmosphere;

DOI:10.1002/aoc.1846

Reference yield:

2.6-bis(hydroxymethyl)pyridine (1195-59-1) → 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1(15),11,13-triene (129135-32-6)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / ethyl acetate / 0.25 h / 0 °C

2: potassium carbonate / acetonitrile / 9 h / Reflux

With potassium carbonate; triethylamine; In ethyl acetate; acetonitrile;

DOI:10.1021/jo5002559

Reference yield:

N-(p-toluenesulfonyl)aziridine (3634-89-7) → 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1(15),11,13-triene (129135-32-6)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene / 1 h / 120 °C / Microwave irradiation; Sealed tube

2: potassium carbonate / acetonitrile / 9 h / Reflux

With potassium carbonate; In toluene; acetonitrile;

DOI:10.1021/jo5002559

upstream raw materials:

2,6-bis(chloromethyl)pyridine

N³-benzyl-N¹,N⁵-ditosyl-3-aza-1,5-pentanediamine

2-(tosylamino)ethyl p-toluenesulfonate

N-(p-toluenesulfonyl)aziridine

Downstream raw materials:

C₃₂H₃₆AgN₄O₄S₂⁽¹⁺⁾*CF₃O₃S^(1-)

C₃₂H₃₆AgN₄O₄S₂⁽¹⁺⁾*C₂F₆NO₄S₂^(1-)

C₃₂H₃₆CuN₄O₄S₂⁽¹⁺⁾*CF₃O₃S^(1-)

C₃₂H₃₆N₄O₄S₂*CHF₃O₃S

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 129135-32-6 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene

Send

Send

Metric Ton KG G Pound L ML

Send

Send