3,5-diaminobenzoyl azide

Base Information

• Chemical Name: 3,5-diaminobenzoyl azide
• CAS No.: 213212-88-5
• Molecular Formula: C₇H₇N₅O
• Molecular Weight: 177.165
• Mol file: 213212-88-5.mol

Synonyms:3,5-diaminobenzoyl azide

Chemical Property of 3,5-diaminobenzoyl azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,5-diaminobenzoyl azide

There total 4 articles about 3,5-diaminobenzoyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

(3-Azidocarbonyl-5-tert-butoxycarbonylamino-phenyl)-carbamic acid tert-butyl ester (213680-79-6) → 3,5-diaminobenzoyl azide (213212-88-5)

Guidance literature:

With trifluoroacetic acid; In dichloromethane;

DOI:10.1039/a803676d

Reference yield:

3.5-diaminobenzoic acid (535-87-5) → 3,5-diaminobenzoyl azide (213212-88-5)

Guidance literature:

Multi-step reaction with 4 steps

1: 96 percent / Et₃N / methanol

2: Et₃N / tetrahydrofuran / 0 °C

3: NaN₃ / H₂O

4: 77 percent / TFA / CH₂Cl₂

With sodium azide; triethylamine; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane; water;

DOI:10.1039/a803676d

Reference yield:

3,5-di-(tert-butyloxycarbonylamino)benzoic acid (133887-83-9) → 3,5-diaminobenzoyl azide (213212-88-5)

Guidance literature:

Multi-step reaction with 3 steps

1: Et₃N / tetrahydrofuran / 0 °C

2: NaN₃ / H₂O

3: 77 percent / TFA / CH₂Cl₂

With sodium azide; triethylamine; trifluoroacetic acid; In tetrahydrofuran; dichloromethane; water;

DOI:10.1039/a803676d

upstream raw materials:

(3-Azidocarbonyl-5-tert-butoxycarbonylamino-phenyl)-carbamic acid tert-butyl ester

3.5-diaminobenzoic acid

3,5-di-(tert-butyloxycarbonylamino)benzoic acid