3-(trimethylsilyl)prop-2-ynyl cinnamate

Base Information

• Chemical Name: 3-(trimethylsilyl)prop-2-ynyl cinnamate
• CAS No.: 126571-11-7
• Molecular Formula: C₁₅H₁₈O₂Si
• Molecular Weight: 258.392
• Mol file: 126571-11-7.mol

Synonyms:3-(trimethylsilyl)prop-2-ynyl cinnamate

Chemical Property of 3-(trimethylsilyl)prop-2-ynyl cinnamate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 3-(trimethylsilyl)prop-2-ynyl cinnamate

There total 1 articles about 3-(trimethylsilyl)prop-2-ynyl cinnamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

prop-2-ynyl 3-phenylacrylate (91368-35-3,29584-63-2) + trimethylsilyl trifluoromethanesulfonate (27607-77-8) → 3-(trimethylsilyl)prop-2-ynyl cinnamate (126571-11-7)

Guidance literature:

With zinc trifluoromethanesulfonate; triethylamine; In dichloromethane; at 23 ℃; for 12h;

DOI:10.1021/jo702557d

Reference yield:

3-(trimethylsilyl)prop-2-ynyl cinnamate (126571-11-7) → (E)-3-Phenyl-acrylic acid (Z)-3-trimethylsilanyl-allyl ester (126571-13-9,126571-14-0)

Guidance literature:

With acetic acid; tris-(o-tolyl)phosphine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In benzene; for 1.4h; Yield given; Ambient temperature;

DOI:10.1016/S0040-4039(01)80767-X

upstream raw materials:

prop-2-ynyl 3-phenylacrylate

trimethylsilyl trifluoromethanesulfonate

Downstream raw materials:

(E)-3-Phenyl-acrylic acid (Z)-3-trimethylsilanyl-allyl ester