Vinyl nonafluoro-1-butanesulfonate

Base Information

• Chemical Name: Vinyl nonafluoro-1-butanesulfonate
• CAS No.: 42409-05-2
• Molecular Formula: C6H3 F9 O3 S
• Molecular Weight: 326.14
• Hs Code.: 2905290000
• European Community (EC) Number: 622-803-0
• DSSTox Substance ID: DTXSID00399941
• Nikkaji Number: J1.654.884G
• Wikidata: Q82202728
• Mol file: 42409-05-2.mol

Synonyms:Vinyl nonafluoro-1-butanesulfonate;42409-05-2;ethenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate;SCHEMBL2261463;DTXSID00399941;SZQVETPSXXBSDR-UHFFFAOYSA-N;Nonafluoro-1-butanesulfonic acid vinyl ester

Chemical Property of Vinyl nonafluoro-1-butanesulfonate

Chemical Property:

• PSA: 51.75000
• Density: 1.7 g/mL at 20 °C(lit.)
• LogP: 3.98280
• Storage Temp.: −20°C
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 5
• Exact Mass: 325.96591859
• Heavy Atom Count: 19
• Complexity: 444

Purity/Quality:

98%Min ^*data from raw suppliers

VINYL NONAFLUORO-1-BUTANESULFONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=COS(=O)(=O)C(C(C(C(F)(F)F)(F)F)(F)F)(F)F

Technology Process of Vinyl nonafluoro-1-butanesulfonate

There total 3 articles about Vinyl nonafluoro-1-butanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + Nonafluorobutanesulfonyl fluoride (375-72-4) → vinyl nonafluorobutane-1-sulfonate (42409-05-2)

Guidance literature:

tetrahydrofuran; With n-butyllithium; In hexane; at 35 ℃; for 3h;

Nonafluorobutanesulfonyl fluoride; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 16h; Further stages.;

DOI:10.1002/1099-0690(200111)2001:22<4189::AID-EJOC4189>3.0.CO;2-I

Reference yield: 66.0%

trimethylsiloxyethene (6213-94-1) + Nonafluorobutanesulfonyl fluoride (375-72-4) → vinyl nonafluorobutane-1-sulfonate (42409-05-2)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 16h;

DOI:10.1002/1099-0690(200111)2001:22<4189::AID-EJOC4189>3.0.CO;2-I

Reference yield:

→ vinyl nonafluorobutane-1-sulfonate (42409-05-2)

Guidance literature:

Acetylen, Nonafluorbutansulfonsaeure, HgO; bei 30 Torr in Falle bei -78grad aufgefangen;

upstream raw materials:

tetrahydrofuran

Nonafluorobutanesulfonyl fluoride

trimethylsiloxyethene

Downstream raw materials:

3-bromostyrene

ethyl 4-vinylbenzoate

1-vinylnaphthalene

1-dodecene-3-yne

Refernces