6213-94-1

Basic information

• Product Name: VINYLOXYTRIMETHYLSILANE
• Synonyms: VINYLOXYTRIMETHYLSILANE;(ethenyloxy)trimethyl-silan;(ethenyloxy)trimethyl-Silane;trimethyl(vinyloxy)silane;(Trimethylsilyloxy)ethene;(Trimethylsiloxy)ethylene, TMSO-ethene;(Trimethylsilyl)vinyl ether;Ethenyl(trimethylsilyl) ether
• CAS NO: 6213-94-1
• Molecular Formula: C₅H₁₂OSi
• Molecular Weight: 116.23
• EINECS: 228-281-7
• Product Categories: monomer;Monoalkoxysilanes;Si (Classes of Silicon Compounds);Si-O Compounds;Enol Ethers;Building Blocks;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds
• Mol File: 6213-94-1.mol
• Article Data: 22

Chemical Properties

• Melting Point: <0°C
• Boiling Point: 74 °C(lit.)
• Flash Point: −2 °F
• Appearance: Clear light yellow/Liquid
• Density: 0.779 g/mL at 25 °C(lit.)
• Vapor Pressure: 115mmHg at 25°C
• Refractive Index: n20/D 1.389(lit.)
• Storage Temp.: 0-6°C
• Sensitive: Moisture Sensitive
• BRN: 1738846
• CAS DataBase Reference: VINYLOXYTRIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: VINYLOXYTRIMETHYLSILANE(6213-94-1)
• EPA Substance Registry System: VINYLOXYTRIMETHYLSILANE(6213-94-1)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 3
• F: 10
• TSCA: Yes
• HazardClass: 3
• PackingGroup: II
• Hazardous Substances Data: 6213-94-1(Hazardous Substances Data)

Usage

Chemical Properties

clear light yellow liquid

InChI:InChI=1/C5H12OSi/c1-5-6-7(2,3)4/h5H,1H2,2-4H3

Upstream product

• 506-96-7 Acetyl bromide 
• 78240-74-1 K⁽¹⁺⁾*(CO)4FeSi(CH₃)3^(1-)=K[(CO)4FeSi(CH₃)3] 
• 75-77-4 chloro-trimethyl-silane 
• 557-75-5 ethenol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 27652-48-8 (Tripropylstannyl)acetaldehyd 
• 33581-77-0 trimethylsilyl [(trimethylsilyl)oxy]acetate 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 75-07-0 acetaldehyde 
• 107-18-6 allyl alcohol 
• 21438-92-6 C₁₉H₂₂OSi 
• 107-21-1 ethylene glycol 
• 56002-69-8 trimethyl-(1H,1H,3H-tetrafluoropropoxy)silane 
• 78847-14-0 3-Methyl-5-trimethylsilanyl-4,5-dihydro-isoxazole 

Downstream Products

• 99074-89-2 2-(N,N-dimethyl-4-aminophenyl)acetaldehyde 
• 252349-38-5 (1R)-2-tert-butoxy-1-methyl-2-oxoethyl (2R)-2-(5-chloro-2-iodoanilino)-4-oxobutanoate 
• 71271-00-6 N-(3-hydroxy-2-oxopropyl)-2',6'-dimethylmethanesulphonanilide 
• 791114-74-4 ((2,6-i-Pr2-C6H3)NCMeCMeN(2,6-i-Pr2-C6H3))Pd(η3-C3H5)(1+) 

Relevant articles and documents

CONVERSION OF SOME ALKENYLTRIMETHYLSILANES INTO SILYL ENOL ETHERS

The cycloaddition products (5-trimethylsilylisoxazolines) between alkenyltrimethylsilanes and acetonitrile oxide undergo thermolytic rearrangement-cycloreversion to afford silyl enol ethers of retained stereochemistry vs. the starting alkenylsilanes.

Efficient room-temperature O-silylation of alcohols using a SBA-15-supported cobalt(II) nanocatalyst

The O-silylation of OH groups of alcohols and phenols with hexamethyldisilazane (HMDS) was achieved in high-to-excellent yields using catalytic quantities of a SBA-15-supported cobalt(II) nanocatalyst (typically 0.5 mol-%) at room temperature and under solvent-free conditions. Furthermore, the heterogeneous catalyst showed an excellent durability and can be conveniently reused by filtration for at least twelve times without any noticeable loss of activity. Copyright

Synthesis of vinyl carbonates for use in producing vinyl carbamates

A method for making a vinyl carbonate represented by the formula (I): CH2═CHOC(O)X1R1??(I) wherein X1is oxygen or sulfur and R1is a substituted or an unsubstituted aliphatic alkyl, aryl, aryl alkyl, olefinic, vinyl, or cycloaliphatic group comprises: (a) reacting a compound represented by the formula (II): X2C(O)X1R1??(II) ?wherein X2is a halogen other than fluorine, with a compound represented by the formula (III): M1—F??(III) ?wherein M1is selected from a Group IA metal, in the presence of a first phase transfer catalyst and a first organic solvent, to form a compound represented by the formula (IV): FC(O)X1R1??(IV) and (b) reacting a compound represented by the formula (IV) with a compound represented by the formula (V): CH2═CHOSi(R2)3??(V) ?wherein R2is a substituted or an unsubstituted aliphatic alkyl, aryl, aryl alkyl olefinic, vinyl, or cycloaliphatic group, or any combination thereof, in the presence of a metal salt represented by the formula M2—F wherein M2is a Group IA metal, a second phase transfer catalyst, and a second organic solvent, to form the compound represented by formula (I).