(1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide

Base Information

• Chemical Name: (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide
• CAS No.: 82769-86-6
• Molecular Formula: C₂₆H₃₃NO₆S
• Molecular Weight: 487.617
• Mol file: 82769-86-6.mol

Synonyms:(1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide

Chemical Property of (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide

There total 1 articles about (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((S)-1-Phenyl-ethyl)-carbamic acid 2,2,3a,7-tetramethyl-5-phenylsulfanyl-hexahydro-benzo[1,3]dioxol-4-yl ester (82769-84-4,82769-85-5) → (1'S,1R,2R,3S,4S,6R)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide (82769-87-7) + (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide (82769-86-6)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 1.) -35 deg C, 10 min, 2.) -35 deg C -> 25 deg C, 1 h;

DOI:10.1021/ja00385a030

Reference yield: 86.0%

(1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylsulfonyl)cyclohexane-1,2-diol 1,2-acetonide (82769-86-6) → (3αS,4S,7αR)-2,2,4,7α-tetramethyl-6-(phenylsulfonyl)-3α,4,5,7α-tetrahydrobenzo[δ][1,3]dioxole (82796-48-3)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; for 16h; Heating;

DOI:10.1021/ja00385a030

upstream raw materials:

((S)-1-Phenyl-ethyl)-carbamic acid 2,2,3a,7-tetramethyl-5-phenylsulfanyl-hexahydro-benzo[1,3]dioxol-4-yl ester

Downstream raw materials:

(3αS,4S,7αR)-2,2,4,7α-tetramethyl-6-(phenylsulfonyl)-3α,4,5,7α-tetrahydrobenzo[δ][1,3]dioxole