2-methyl-1-phenyl-2,5-dihydro-1H-phosphole 1-oxide

Base Information

Chemical Name:2-methyl-1-phenyl-2,5-dihydro-1H-phosphole 1-oxide
CAS No.:15450-91-6
Molecular Formula:C11H13 O P
Molecular Weight:192.197
Hs Code.:
Mol file:15450-91-6.mol

Synonyms:3-Phospholene,2-methyl-1-phenyl-, 1-oxide (7CI,8CI);2-Methyl-1-phenyl-2,5-dihydro-1H-phosphole 1-oxide; NSC 222485

Suppliers and Price of 2-methyl-1-phenyl-2,5-dihydro-1H-phosphole 1-oxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of 2-methyl-1-phenyl-2,5-dihydro-1H-phosphole 1-oxide

Chemical Property:

Vapor Pressure:4.33E-05mmHg at 25°C
Boiling Point:361.4°Cat760mmHg
Flash Point:172.4°C
Density:1.1g/cm³

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-methyl-1-phenyl-2,5-dihydro-1H-phosphole 1-oxide

There total 11 articles about 2-methyl-1-phenyl-2,5-dihydro-1H-phosphole 1-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 5186-73-2
1-phenyl-3-phospholene 1-oxide

: 74-88-4
methyl iodide

: 38987-29-0
2,5-dimethyl-1-phenyl-3-phospholene 1-oxide

: 15450-91-6,27795-43-3,27795-44-4
trans-2-methyl-1-phenyl-3-phospholene 1-oxide

Guidance literature:: 1-phenyl-3-phospholene 1-oxide; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.166667h;

methyl iodide; In tetrahydrofuran; at -78 ℃; for 0.5h;
DOI:10.1016/j.tet.2004.12.004

Reference yield: 59.0%

: 5186-73-2
1-phenyl-3-phospholene 1-oxide

: 74-88-4
methyl iodide

: 15450-91-6,27795-43-3,27795-44-4
trans-2-methyl-1-phenyl-3-phospholene 1-oxide

Guidance literature:: 1-phenyl-3-phospholene 1-oxide; With lithium diisopropyl amide; at -78 ℃; for 0.166667h;

methyl iodide; at -78 ℃; for 1h;
DOI:10.1016/j.tet.2003.08.028

Reference yield:

: 504-60-9,17410-45-6,25212-15-1,64940-84-7
penta-1,3-diene

: 15450-91-6,27795-43-3,27795-44-4
2r-methyl-1-phenyl-2,5-dihydro-1H-phosphole 1t-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: copper stearate

2: NaHCO₃

With copper octadecanoate; sodium hydrogencarbonate;
DOI:10.1021/ja00717a028