phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

Base Information

Chemical Name:phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside
CAS No.:1309377-88-5
Molecular Formula:C₄₇H₅₃NO₁₀S
Molecular Weight:824.005
Hs Code.:

Synonyms:phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

Suppliers and Price of phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

There total 7 articles about phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 741677-99-6
phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-hydroxy-1-thio-β-D-galactopyranoside

: 39945-54-5
benzyl N-(3-bromopropyl)carbamate

: 1309377-88-5
phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

Guidance literature:: phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-hydroxy-1-thio-β-D-galactopyranoside; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at -10 ℃; for 0.5h; Inert atmosphere;

benzyl N-(3-bromopropyl)carbamate; In N,N-dimethyl-formamide; mineral oil; at -10 - 20 ℃; for 24.5h; Inert atmosphere;
DOI:10.1016/j.bmc.2011.03.023

Reference yield:

: 16758-34-2
1-thiophenyl-β-D-galactopyranoside

: 1309377-88-5
phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridine; triethylamine / 21.33 h / -10 - 20 °C / Inert atmosphere

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 4.5 h / -10 - 20 °C

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 7 h / 0 - 20 °C / Molecular sieve; Inert atmosphere

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / -10 °C / Inert atmosphere

4.2: 24.5 h / -10 - 20 °C / Inert atmosphere

With pyridine; tetrabutyl ammonium fluoride; sodium hydride; triethylamine; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil;
DOI:10.1016/j.bmc.2011.03.023

Reference yield:

: 1309377-87-4
phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(tertbutyldimethylsiloxypropyl)-1-thio-β-D-galactopyranoside

: 1309377-88-5
phenyl 2,3,4-tri-O-(4-methoxybenzyl)-6-O-(3-benzyloxycarbonylaminopropyl)-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 7 h / 0 - 20 °C / Molecular sieve; Inert atmosphere

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / -10 °C / Inert atmosphere

2.2: 24.5 h / -10 - 20 °C / Inert atmosphere

With tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil;
DOI:10.1016/j.bmc.2011.03.023