[(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester

Base Information

Chemical Name:[(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester
CAS No.:153788-92-2
Molecular Formula:C₁₇H₂₄O₅
Molecular Weight:308.375
Hs Code.:

Synonyms:[(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester

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Chemical Property of [(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester

Chemical Property:

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Technology Process of [(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester

There total 1 articles about [(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-52-7
benzaldehyde

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 152377-62-3
(2R,3R,4R)-1-(tert-butyldimethylsilyloxy)-2,4-dimethylhex-5-en-3-ol

: 153788-92-2
[(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester

Guidance literature:: With 2,3-dimercapto-succinic acid; potassium hexamethylsilazane; pyridine hydrogenfluoride; ozone; Yield given. Multistep reaction;

Reference yield:

: 153788-92-2
[(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester

: 153788-94-4
2,2-Dimethyl-propionic acid (Z)-(4R,5S,6R,9R)-5-(tert-butyl-dimethyl-silanyloxy)-10-[(2R,3R,4R,5S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-phenylsulfanyl-tetrahydro-pyran-2-yl]-9-hydroxy-2,4,6-trimethyl-dec-2-en-7-ynyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Dess-Martin reagent, Amberlyst, 2.) CSA

2: 99 percent / lutidine

3: 1.) LiOH, HNMe(OMe), DCC, HOBT, 2.) ZnI₂, Bu₄NI, 3.) LiAlH₄

4: NiCl₂, CrCl₂ / 1.) THF

5: 1.) Swern reagent, 2.) catecholborane, B-butyloxazaborolidine

With chromium dichloride; lithium hydroxide; lithium aluminium tetrahydride; swern reagent; Amberlyst; B-butyloxazaborolidine; lutidine; camphor-10-sulfonic acid; tetra-(n-butyl)ammonium iodide; benzotriazol-1-ol; Dess-Martin periodane; dicyclohexyl-carbodiimide; zinc(II) iodide; nickel dichloride; N,0-dimethylhydroxylamine; benzo[1,3,2]dioxaborole;

Reference yield:

: 153788-92-2
[(2R,4R,5R,6S)-6-((R)-2-Hydroxy-1-methyl-ethyl)-5-methyl-2-phenyl-[1,3]dioxan-4-yl]-acetic acid methyl ester

: 153788-86-4
[(2R,3R,4R,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-phenylsulfanyl-tetrahydro-pyran-2-yl]-acetaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Dess-Martin reagent, Amberlyst, 2.) CSA

2: 99 percent / lutidine

3: 1.) LiOH, HNMe(OMe), DCC, HOBT, 2.) ZnI₂, Bu₄NI, 3.) LiAlH₄

With lithium hydroxide; lithium aluminium tetrahydride; Amberlyst; lutidine; camphor-10-sulfonic acid; tetra-(n-butyl)ammonium iodide; benzotriazol-1-ol; Dess-Martin periodane; dicyclohexyl-carbodiimide; zinc(II) iodide; N,0-dimethylhydroxylamine;