Methanone, phenyl(2,4,6-tris(methylethyl)phenyl)-

Base Information

• Chemical Name: Methanone, phenyl(2,4,6-tris(methylethyl)phenyl)-
• CAS No.: 33574-11-7
• Molecular Formula: C22H28 O
• Molecular Weight: 308.464
• DSSTox Substance ID: DTXSID30187272
• Nikkaji Number: J213.051C
• Wikidata: Q83058910
• Mol file: 33574-11-7.mol

Synonyms:2,4,6-Triisopropylbenzophenone;Methanone, phenyl(2,4,6-tris(methylethyl)phenyl)-;33574-11-7;Methanone, phenyl[2,4,6-tris(methylethyl)phenyl]-;SCHEMBL10349532;DTXSID30187272;7236-12-6

Chemical Property of Methanone, phenyl(2,4,6-tris(methylethyl)phenyl)-

Chemical Property:

• Vapor Pressure: 1.59E-07mmHg at 25°C
• Boiling Point: 427.8°Cat760mmHg
• Flash Point: 182.5°C
• Density: 0.97g/cm³
• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 308.214015512
• Heavy Atom Count: 23
• Complexity: 357

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=CC(=C(C(=C1)C(C)C)C(=O)C2=CC=CC=C2)C(C)C

Technology Process of Methanone, phenyl(2,4,6-tris(methylethyl)phenyl)-

There total 5 articles about Methanone, phenyl(2,4,6-tris(methylethyl)phenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

3',5'-diisopropyl-4,4-dimethyl-3-phenyl-1,2-benzocyclobuten-3-ol (33574-16-2) → 2,4,6-triisopropylbenzophenone (33574-11-7) + 1,3-diisopropyl-10,10-dimethylanthrone (86177-63-1)

Guidance literature:

With acetophenone; In benzene; for 15h; Irradiation;

DOI:10.1021/ja00343a008

Reference yield:

1,3,5-triisopropyl benzene (717-74-8) + benzoyl chloride (98-88-4) → 2,4,6-triisopropylbenzophenone (33574-11-7)

Guidance literature:

With carbon disulfide; aluminium trichloride;

DOI:10.1021/ja01263a013

Reference yield:

3',5'-diisopropyl-4,4-dimethyl-3-phenyl-1,2-benzocyclobuten-3-ol (33574-16-2) → 2,4,6-triisopropylbenzophenone (33574-11-7) + 1,3-diisopropyl-10,10-dimethylanthrone (86177-63-1) + 1,4-dihydro-1-hydroxy-6,8-diisopropyl-4,4-dimethyl-1-phenyl-2,3-benzodioxin (86177-64-2)

Guidance literature:

With oxygen; In various solvent(s); at 134 ℃; for 4h; Product distribution; also in the absence of O₂ at 135 deg C;

DOI:10.1021/ja00354a010

upstream raw materials:

1,3,5-triisopropyl benzene

benzoyl chloride

3',5'-diisopropyl-4,4-dimethyl-3-phenyl-1,2-benzocyclobuten-3-ol

Downstream raw materials:

2-<2,4,6-triisopropylphenyl>-2,3,3-triphenylthiirane

1-<2,4,6-triisopropylphenyl>-1,2,2-triphenylethylene

1,4-bis-(2,4,6-triisopropyl-benzoyl)-benzene

2,4,6-triisopropylthiobenzophenone