allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

Base Information

Chemical Name:allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate
CAS No.:1451144-21-0
Molecular Formula:C₂₃H₂₁NO₆S
Molecular Weight:439.489
Hs Code.:

Synonyms:allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

Suppliers and Price of allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

There total 1 articles about allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 1451144-16-3
allyl 4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

: 98-68-0
4-methoxy-phenyl-sulphonyl chloride

: 1451144-21-0
allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

Guidance literature:: With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide; In dichloromethane; water; at 0 ℃; for 3h;
DOI:10.1071/CH13287

Reference yield: 79.0%

: 1451144-21-0
allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

: 1451144-24-3
C₂₇H₂₇NO₈S

Guidance literature:: allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.333333h;

ethyl halidoacetate; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; for 2h;
DOI:10.1071/CH13287

Reference yield:

: 1451144-21-0
allyl 9-((4-methoxyphenyl)sulfonyl)-4-oxo-2,3,4,9-tetrahydro-1H-carbazole-3-carboxylate

: 1451144-35-6
C₂₆H₂₇NO₆S

: C₂₆H₂₇NO₆S

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / mineral oil; tetrahydrofuran / 0.33 h / 0 °C

1.2: 2 h / 0 - 20 °C

2.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (4S)-2-[2-(diphenylphosphino)phenyl]-4-isopropyl-4,5-dihydro-1,3-oxazole / toluene / 4 h / 80 °C / Inert atmosphere

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium hydride; (4S)-2-[2-(diphenylphosphino)phenyl]-4-isopropyl-4,5-dihydro-1,3-oxazole; In tetrahydrofuran; toluene; mineral oil;
DOI:10.1071/CH13287