(S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

Base Information

Chemical Name:(S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole
CAS No.:222533-64-4
Molecular Formula:C₂₉H₃₀N₂O₃
Molecular Weight:454.569
Hs Code.:

Synonyms:(S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

Suppliers and Price of (S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

Chemical Property:

Purity/Quality:

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Technology Process of (S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

There total 6 articles about (S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7135-32-2
1-benzylindolin-2-one

: 222533-64-4
(S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) n-BuLi / 1.) THF, hexane, 2.) THF, hexane

2: 1.) n-BuLi / 1.) ether, hexane, -78 -> 0 deg C, 2.) ether, hexane, -78 -> 0 deg C

3: 97 percent / NaBH₄ / dioxane; methanol

4: 87 percent / sodium nitrite, acetic acid / dimethylsulfoxide

5: 1.) triethylamine, diphenylphosphoryl azide / 1.) toluene, reflux, 2.) toluene, reflux

With sodium tetrahydroborate; n-butyllithium; diphenylphosphoranyl azide; acetic acid; triethylamine; sodium nitrite; In 1,4-dioxane; methanol; dimethyl sulfoxide;
DOI:10.1021/jo981577q

Reference yield:

: 870-63-3
prenyl bromide

: 222533-64-4
(S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) n-BuLi / 1.) THF, hexane, 2.) THF, hexane

2: 1.) n-BuLi / 1.) ether, hexane, -78 -> 0 deg C, 2.) ether, hexane, -78 -> 0 deg C

3: 97 percent / NaBH₄ / dioxane; methanol

4: 87 percent / sodium nitrite, acetic acid / dimethylsulfoxide

5: 1.) triethylamine, diphenylphosphoryl azide / 1.) toluene, reflux, 2.) toluene, reflux

With sodium tetrahydroborate; n-butyllithium; diphenylphosphoranyl azide; acetic acid; triethylamine; sodium nitrite; In 1,4-dioxane; methanol; dimethyl sulfoxide;
DOI:10.1021/jo981577q

Reference yield:

: 222533-60-0
1-benzyl-3-(3-methylbut-2-enyl)-1,3-dihydroindol-2-one

: 222533-64-4
(S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) ether, hexane, -78 -> 0 deg C, 2.) ether, hexane, -78 -> 0 deg C

2: 97 percent / NaBH₄ / dioxane; methanol

3: 87 percent / sodium nitrite, acetic acid / dimethylsulfoxide

4: 1.) triethylamine, diphenylphosphoryl azide / 1.) toluene, reflux, 2.) toluene, reflux

With sodium tetrahydroborate; n-butyllithium; diphenylphosphoranyl azide; acetic acid; triethylamine; sodium nitrite; In 1,4-dioxane; methanol; dimethyl sulfoxide;
DOI:10.1021/jo981577q