((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

Base Information

Chemical Name:((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃
CAS No.:79470-05-6
Molecular Formula:C₃₆H₃₁BClF₄IrN₂P₂
Molecular Weight:868.081
Hs Code.:

((C<sub>6</sub>H<sub>5</sub>)3P)2(Cl)(N<sub>2</sub>)(H)IrFBF<sub>3</sub>

Synonyms:((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

Suppliers and Price of ((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

There total 1 articles about ((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: tetrafluoroboric acid diethyletherate

: 15695-36-0,18433-33-5,21414-18-6
trans-{IrCl(N₂)(PPh₃)2}

: 79470-05-6
((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

Guidance literature:: In dichloromethane; (Ar); HBF4-etherate is added at -25°C; stirred (-25°C, 1 h); centrifuged in the cold; washed (3 times, CH2Cl2, -25°C; 3 times, cold pentane); dried (high vac., -20 to 0°C, 8 h); elem. anal.;
DOI:10.1016/S0022-328X(00)99523-8

Reference yield: 92.0%

: 79470-05-6
((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

: 110311-16-5
chloro-dinitrogen-hydrido-methanol-bis(triphenylphosphine)-iridium(III) tetrafluoroborate

Guidance literature:: With methanol; In dichloromethane; (Ar); CH3OH is added at -25°C; stirred (-25°C, 10 min); pentane slowly added; centrifuged; washed (cold pentane); dried (high vac., 5 h, -15 to -5°C); elem. anal.;
DOI:10.1016/S0022-328X(00)99523-8

Reference yield: 92.0%

: 79470-05-6
((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃

: 5502-78-3,137609-04-2
9-Methylguanine

: 99626-35-4
chloro-hydrido-9-methylguanine-bis-(triphenylphosphine)-iridium(III)-tetrafluoroborate

Guidance literature:: In dichloromethane; byproducts: N2; (Ar); mixt. dried (-10°C; high vac.); added at -20°C cooled CH2Cl2; stirred (-25°C; 48 h); stirred (room temp.; 1 h); ppt.; centred; washed (CH2Cl2; two time n-pentane); dried (high vac.; 3 h); dissolved in methanol; filtered; pptd. with Et2O and n-pentane; centrifuged; washed with pentane; dried in high vac.; elem. anal.;