(4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane

Base Information

Chemical Name:(4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane
CAS No.:247058-37-3
Molecular Formula:C₂₃H₃₆O₃Se
Molecular Weight:439.497
Hs Code.:

Synonyms:(4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane

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Chemical Property of (4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane

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Technology Process of (4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane

There total 7 articles about (4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 247058-36-2
(1R,2S)-1-[(1R)-1-hydroxynonyl]-2-(phenylselanyl)-cyclohexanol

: 149-73-5
trimethyl orthoformate

: 247058-37-3
(4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane

Guidance literature:: With pyridinium p-toluenesulfonate; In N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1521-3773(19990816)38:16<2395::AID-ANIE2395>3.0.CO;2-W

Reference yield:

: 89523-69-3
1-(1-cyclohexen-1-yl)-1-nonanol

: 247058-37-3
(4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane

Guidance literature:: Multi-step reaction with 4 steps

1: Ti(O-iPr)4; L-(+)-diisopropyl tartrate; tBuOOH / CH₂Cl₂ / -20 °C

2: Ti(O-iPr)4; D-(-)-diisopropyl tartrate; tBuOOH / CH₂Cl₂ / -20 °C

3: ethanol / 0 - 20 °C

4: pyridinium p-toluenesulfonate / dimethylformamide / 4 h / 20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; pyridinium p-toluenesulfonate; D-(-)-diisopropyl tartrate; In ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(02)00857-8

Reference yield:

: 247058-35-1
(1R)-1-[(1R,6R)-7-oxabicyclo[4.1.0]hept-1-yl]-1-nonanol

: 247058-37-3
(4R,5R,6S)-2-methoxy-4-octyl-6-(phenylselanyl)-1,3-dioxaspiro[4,5]decane

Guidance literature:: Multi-step reaction with 2 steps

1: ethanol / 0 - 20 °C

2: pyridinium p-toluenesulfonate / dimethylformamide / 4 h / 20 °C

With pyridinium p-toluenesulfonate; In ethanol; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(02)00857-8