1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole)

Base Information

• Chemical Name: 1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole)
• CAS No.: 1262319-47-0
• Molecular Formula: C₂₀H₁₆N₆O
• Molecular Weight: 356.387
• Mol file: 1262319-47-0.mol

Synonyms:1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole)

Chemical Property of 1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole)

There total 1 articles about 1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

1,2,3-Benzotriazole (95-14-7,27556-51-0) + p-methoxybenzyl benzoate (24318-41-0) → 1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole) (1262319-47-0)

Guidance literature:

With dibenzoyl peroxide; In 1,2-dichloro-ethane; at 80 ℃; for 6h; Schlenk technique;

DOI:10.1080/00397911.2019.1615097

Reference yield: 77.0%

1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole) (1262319-47-0) → 3-(4-methoxyphenyl)benzo[e][1,2,4]triazine (40995-15-1) + 1-(4''-methoxybenzyl)-1H-benzo[d][1.2.3]triazole (133349-85-6)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; allylsamarium bromide; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/cjoc.201200989

Reference yield: 65.0%

1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole) (1262319-47-0) → 3-(4-methoxyphenyl)benzo[e][1,2,4]triazine (40995-15-1)

Guidance literature:

With allylsamarium bromide; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1016/j.tetlet.2010.10.093

upstream raw materials:

1,2,3-Benzotriazole

p-methoxybenzyl benzoate

Downstream raw materials:

3-(4-methoxyphenyl)benzo[e][1,2,4]triazine

1-(4''-methoxybenzyl)-1H-benzo[d][1.2.3]triazole