bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl

Base Information

Chemical Name:bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl
CAS No.:172610-37-6
Molecular Formula:C₃₀H₃₄ClTi
Molecular Weight:477.933
Hs Code.:

Synonyms:bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl

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Chemical Property of bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl

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Technology Process of bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl

There total 1 articles about bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: titanium(III) chloride tetrahydrofuran

: Li(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)

: 172610-37-6
bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl

Guidance literature:: In tetrahydrofuran; N2-atmosphere; stirring for 10 min at room temp., refluxing for 48 h; evapn., extn. (MePh), concn., crystn. on cooling (-80°C); NMR spectroscopy;
DOI:10.1021/om00012a005

Reference yield: 72.0%

: 172610-37-6
bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl

: 201230-82-2
carbon monoxide

: 1173710-73-0
(η5-C5Me4Ph)2Ti(CO)2

Guidance literature:: With sodium amalgam; In pentane; under N2; pentane soln. of Ti complex added to sodium amalgam and pentane with stirring; submerged in liq. N2; degassed in high vac.; CO (1 atm)added at -196°C; thawed; stirred at ambient temp. for 18 h; solvent removed in vac.; filtered through Celite; recrystd. from pentane;
DOI:10.1021/om900282u

Reference yield: 70.0%

: 172610-37-6
bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)TiCl

: 917-54-4
methyllithium

: 172610-39-8
bis(1-phenyl-2,3,4,5-tetramethylcyclopentadienyl)Ti(Me)

Guidance literature:: In tetrahydrofuran; diethyl ether; N2-atmosphere; addn. of ether soln. of MeLi to THF soln. of Ti-complex at -30°C, warming to room temp.; evapn., extn. (MePh), evapn., dissoln. (pentane), crystn. on cooling (-80°C); NMR spectroscopy;
DOI:10.1021/om00012a005