ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

Base Information

Chemical Name:ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate
CAS No.:80448-40-4
Molecular Formula:C₁₈H₂₀O₅
Molecular Weight:316.354
Hs Code.:

Synonyms:ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

Suppliers and Price of ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

There total 2 articles about ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80448-39-1
2-carboethoxy-4-methylene-6-methylcyclohexanone

: 94-36-0
dibenzoyl peroxide

: 80448-40-4
ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

: 80448-41-5
ethyl 1-benzoyloxy-cis-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

Guidance literature:: With sodium hydride; In benzene; at 25 ℃; for 1.5h; Yield given. Yields of byproduct given;
DOI:10.1021/ja00368a015

Reference yield:

: 71435-90-0
4-methylene-2-methylcyclohexanone

: 80448-40-4
ethyl 1-benzoyloxy-trans-3-methyl-5-methylene-2-oxocyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / NaOEt / ethanol / 1.) 0 deg C, 2 h, 2.) 25 deg C, 15 h

2: NaH / benzene / 1.5 h / 25 °C

With sodium ethanolate; sodium hydride; In ethanol; benzene;
DOI:10.1021/ja00368a015