1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

Base Information

Chemical Name:1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside
CAS No.:952429-84-4
Molecular Formula:C₃₁H₃₆Cl₃NO₁₀
Molecular Weight:688.987
Hs Code.:

Synonyms:1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

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Chemical Property of 1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

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Technology Process of 1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

There total 2 articles about 1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 952429-83-3
C₂₇H₃₂Cl₃NO₈

: 102423-16-5
allyl 1-benzotriazolyl carbonate

: 952429-84-4
1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

Guidance literature:: With dmap; 4 A molecular sieve; In dichloromethane; at 0 - 20 ℃; for 1h;
DOI:10.1016/j.tetlet.2007.07.036

Reference yield:

: 952429-82-2
[(2S,3R,4R,5S,6R)-2-Allyloxy-5-benzyloxy-6-hydroxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-3-yl]-carbamic acid 2,2,2-trichloro-ethyl ester

: 952429-84-4
1-propenyl 6-O-allyloxycarbonyl-4-O-benzyl-2-deoxy-3-O-(4-methoxybenzyl)-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / [Ir(cod)(H)(MePh₂P)2]PF₆ / tetrahydrofuran / 3 h / 20 °C

2: 98 percent / molecular sieves 4 Angstroem; 4-(dimethylamino)pyridine / CH₂Cl₂ / 1 h / 0 - 20 °C

With dmap; 4 A molecular sieve; [Ir(cod)(H)(MePh₂P)2]PF₆; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tetlet.2007.07.036