Chlorozinc(1+);1-methanidyl-4-methoxybenzene

Base Information

Chemical Name:Chlorozinc(1+);1-methanidyl-4-methoxybenzene
CAS No.:312693-17-7
Molecular Formula:C₈H₉ClOZn
Molecular Weight:222.002
Hs Code.:
DSSTox Substance ID:DTXSID60400188
Mol file:312693-17-7.mol

Synonyms:chlorozinc(1+);1-methanidyl-4-methoxybenzene;DTXSID60400188;J-018340

Suppliers and Price of Chlorozinc(1+);1-methanidyl-4-methoxybenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
4-Methoxybenzylzinc chloride solution 0.5 M in THF
50ml
$ 244.00

Rieke Metals
4-Methoxybenzylzincchloride
100mL
$ 525.00

Rieke Metals
4-Methoxybenzylzincchloride
50mL
$ 372.00

American Custom Chemicals Corporation
4-METHOXYBENZYLZINC CHLORIDE 95.00%
1L
$ 8200.50

American Custom Chemicals Corporation
4-METHOXYBENZYLZINC CHLORIDE 95.00%
500ML
$ 5544.00

American Custom Chemicals Corporation
4-METHOXYBENZYLZINC CHLORIDE 95.00%
100ML
$ 2864.40

Total 11 raw suppliers

Chemical Property of Chlorozinc(1+);1-methanidyl-4-methoxybenzene

Chemical Property:

Vapor Pressure:1.65mmHg at 25°C
Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：9.23000
Density:g/cm³
LogP:2.69790
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:219.963334
Heavy Atom Count:11
Complexity:74.6

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Methoxybenzylzinc chloride solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xn
Statements: 19-22-36/38-40-36/37-11
Safety Statements: 16-26-33-36-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC1=CC=C(C=C1)[CH2-].Cl[Zn+]

Technology Process of Chlorozinc(1+);1-methanidyl-4-methoxybenzene

There total 3 articles about Chlorozinc(1+);1-methanidyl-4-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.8%

: 824-94-2
p-methoxybenzyl chloride

: 7440-66-6
zinc

: 312693-17-7
(4-methoxybenzyl)zinc(II) chloride

Guidance literature:: p-methoxybenzyl chloride; With chloro-trimethyl-silane; In tetrahydrofuran; ethylene dibromide; at 60 - 70 ℃; Inert atmosphere;

zinc; In tetrahydrofuran; ethylene dibromide; for 3h;

Reference yield: 56.0%

: 824-94-2
p-methoxybenzyl chloride

: 7646-85-7,24359-56-6
zinc(II) chloride

: 312693-17-7
(4-methoxybenzyl)zinc(II) chloride

Guidance literature:: zinc(II) chloride; With lithium chloride; at 320 - 450 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;

p-methoxybenzyl chloride; With magnesium; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c5cc10272c

Reference yield:

: 104-92-7
1-bromo-4-methoxy-benzene

: 7646-85-7,24359-56-6
zinc(II) chloride

: 312693-17-7
(4-methoxybenzyl)zinc(II) chloride

Guidance literature:: 1-bromo-4-methoxy-benzene; With magnesium; lithium chloride; In tetrahydrofuran; at 0 ℃; for 2h; Schlenk technique; Inert atmosphere;

zinc(II) chloride; In tetrahydrofuran; at 0 - 20 ℃; for 0.25h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.9b04564