Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester

Base Information

• Chemical Name: Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester
• CAS No.: 82755-06-4
• Molecular Formula: C₉₁H₁₆₀N₂O₁₅
• Molecular Weight: 1522.28
• Mol file: 82755-06-4.mol

Synonyms:Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester

Chemical Property of Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester

There total 1 articles about Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Hexadecanoic acid (2R,3S,4R,5R,6R)-6-((2R,3S,4R,5R,6R)-6-allyloxy-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-tetrahydro-pyran-2-ylmethoxy)-4-benzyloxy-5-hexadecanoylamino-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester (82755-05-3) → Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester (82755-06-4)

Guidance literature:

With (1,5-cyclooctadiene)bis(methyldiphenylphosphine) iridium hexafluorophosphate; In tetrahydrofuran; at 35 ℃; for 4h;

DOI:10.1016/S0040-4039(00)87231-7

Reference yield: 90.0%

octanoic acid anhydride (623-66-5) + Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester (82755-06-4) → Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-octanoyloxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester (82771-23-1)

Guidance literature:

With dmap; In tetrahydrofuran; pyridine; at 35 ℃; for 1.5h;

upstream raw materials:

Hexadecanoic acid (2R,3S,4R,5R,6R)-6-((2R,3S,4R,5R,6R)-6-allyloxy-5-hexadecanoylamino-4-hexadecanoyloxy-3-hydroxy-tetrahydro-pyran-2-ylmethoxy)-4-benzyloxy-5-hexadecanoylamino-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester

Downstream raw materials:

Hexadecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-5-hexadecanoylamino-6-{(2R,3S,4R,5R,6R)-5-hexadecanoylamino-4-hexadecanoyloxy-3-octanoyloxy-6-[((E)-propenyl)oxy]-tetrahydro-pyran-2-ylmethoxy}-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-ylmethyl ester