(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde

Base Information

Chemical Name:(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde
CAS No.:1240893-16-6
Molecular Formula:C₂₀H₂₁NO₅
Molecular Weight:355.39
Hs Code.:

Synonyms:(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde

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Technology Process of (4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde

There total 1 articles about (4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1240893-36-0
(4S,5S)-4-(benzyloxymethyl)-5-(hydroxymethyl)-3-(4-methoxybenzyl)oxazolidin-2-one

: 1240893-16-6
(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 4h; Inert atmosphere;
DOI:10.1039/c004218h

Reference yield: 87.0%

: 629-05-0
n-octyne

: 1240893-16-6
(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde

: 1312549-85-1
(4S,5S)-4-(benzyloxymethyl)-5-((R)-1-hydroxynon-2-ynyl)-3-(4-methoxybenzyl) oxazolidin-2-one

Guidance literature:: n-octyne; With n-butyllithium; In tetrahydrofuran; hexane; at -20 ℃;

With cerium(III) chloride; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde; diastereoselective reaction; Further stages;
DOI:10.1016/j.tet.2011.04.027

Reference yield: 65.0%

: 1240893-16-6
(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde

: 89343-06-6
tris-iso-propylsilyl acetylene

: 1240893-59-7
(4S,5S)-4-(benzyloxymethyl)-5-((R)-1-hydroxy-3-(triisopropylsilyl)prop-2-ynyl)-3-(4-methoxybenzyl)oxazolidin-2-one

Guidance literature:: tris-iso-propylsilyl acetylene; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; Inert atmosphere;

With cerium(III) chloride; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

(4S,5S)-4-(benzyloxymethyl)-3-(4-methoxybenzyl)-2-oxooxazolidine-5-carbaldehyde; In tetrahydrofuran; hexane; at -78 ℃; for 6h; Inert atmosphere;
DOI:10.1039/c004218h