TETRAHYDRO-7-(METHOXYCARBONYLAMINO)-2,2-

Base Information

Chemical Name:TETRAHYDRO-7-(METHOXYCARBONYLAMINO)-2,2-
CAS No.:312623-98-6
Molecular Formula:C₁₃H₁₉NO₆
Molecular Weight:285.297
Hs Code.:
Mol file:312623-98-6.mol

Synonyms:Carbamicacid, [(3aS,4R,7S,7aR)-7-(acetyloxy)-3a,4,7,7a-tetrahydro-2,2-dimethyl-1,3-benzodioxol-4-yl]-,methyl ester (9CI)

Suppliers and Price of TETRAHYDRO-7-(METHOXYCARBONYLAMINO)-2,2-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of TETRAHYDRO-7-(METHOXYCARBONYLAMINO)-2,2-

Chemical Property:

Vapor Pressure:3.07E-06mmHg at 25°C
Melting Point:98-101 °C(lit.)
Refractive Index:1.514
Boiling Point:388.4°Cat760mmHg
Flash Point:188.7°C
PSA：83.09000
Density:1.24g/cm³
LogP:1.12350

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of TETRAHYDRO-7-(METHOXYCARBONYLAMINO)-2,2-

There total 8 articles about TETRAHYDRO-7-(METHOXYCARBONYLAMINO)-2,2- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 312623-98-6
(1S,2S,3S,6R)-6-(N-carbomethoxy)amino-1,2-O-isopropylidene-3-acetyloxycyclohex-4-ene-1,2-diol

Guidance literature:: Multi-step reaction with 7 steps

1: Escherichia coli JM₁₀₉ (DTG₆₀₁)

2: Bu₃SnH, AIBN / tetrahydrofuran

3: p-TsOH

4: NaIO₄ / methanol; H₂O

5: Al(Hg) / tetrahydrofuran; H₂O

6: pyridine

With pyridine; sodium periodate; aluminum amalgam; 2,2'-azobis(isobutyronitrile); Escherichia coli JM₁₀₉ (DTG₆₀₁); tri-n-butyl-tin hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; water;
DOI:10.1016/S0040-4039(99)00434-7

Reference yield:

: 82683-92-9
1-Bromo-2,3-dihydroxy-cyclohexa-4,6-diene

: 312623-98-6
(1S,2S,3S,6R)-6-(N-carbomethoxy)amino-1,2-O-isopropylidene-3-acetyloxycyclohex-4-ene-1,2-diol

Guidance literature:: Multi-step reaction with 5 steps

1: p-TsOH

2: NaIO₄ / methanol; H₂O

3: Al(Hg) / tetrahydrofuran; H₂O

4: pyridine

With pyridine; sodium periodate; aluminum amalgam; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; water;
DOI:10.1016/S0040-4039(99)00434-7

Reference yield:

: (1S,2S)-3-bromo-1,2-isopropylidenedioxycyclohexa-3,5-diene

: 312623-98-6
(1S,2S,3S,6R)-6-(N-carbomethoxy)amino-1,2-O-isopropylidene-3-acetyloxycyclohex-4-ene-1,2-diol

Guidance literature:: Multi-step reaction with 4 steps

1: NaIO₄ / methanol; H₂O

2: Al(Hg) / tetrahydrofuran; H₂O

3: pyridine

With pyridine; sodium periodate; aluminum amalgam; In tetrahydrofuran; methanol; water;
DOI:10.1016/S0040-4039(99)00434-7