RhCl(PEt₂Ph₃)3

Base Information

• Chemical Name: RhCl(PEt₂Ph₃)3
• CAS No.: 25504-23-8
• Molecular Formula: C₃₀H₄₅ClP₃Rh
• Molecular Weight: 636.967
• Mol file: 25504-23-8.mol

Synonyms:RhCl(PEt₂Ph₃)3

Chemical Property of RhCl(PEt₂Ph₃)3

Chemical Property:

Purity/Quality:

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Technology Process of RhCl(PEt₂Ph₃)3

There total 2 articles about RhCl(PEt₂Ph₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

mer-Rh(C6H5PEt2)3Cl3 (15137-12-9,16634-14-3,21839-98-5) → RhCl(PEt2Ph3)3 (25504-23-8)

Guidance literature:

With sodium carbonate; In toluene; byproducts: NaCl, POEt2Ph; reagents mixed, heated to 353 K; after 24 h NaCl sepd. from the soln., isolated by filtration, crystallized from pentane, elem. anal.;

DOI:10.1002/1099-0682(200107)2001:7<1801::AID-EJIC1801>3.0.CO;2-X

Reference yield:

RhCl(η(2)-O2)(PEt2Ph)3 + carbon dioxide (124-38-9,18923-20-1) → mer-Rh(C6H5PEt2)3Cl3 (15137-12-9,16634-14-3,21839-98-5) + trans-RhCl(CO)(PEt2Ph)2 (15691-93-7,29553-46-6) + RhCl(PEt2Ph3)3 (25504-23-8) + mer-RhCl(CO3)(PEt2Ph3)3 (360783-38-6)

Guidance literature:

In dichloromethane-d2; byproducts: O=PEt2Ph; absence of air and moisture; warming from 213 to 273 K, standing for fewmin; not isolated, reaction followed by NMR spectroscopy;

Reference yield:

RhCl(PEt2Ph3)3 (25504-23-8) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → Rh(1+)*3C6H5P(C2H5)2*SO2*Cl(1-)=Rh(C6H5P(C2H5)2)3(SO2)Cl

Guidance literature:

DOI:10.1039/DT9750002218

upstream raw materials:

mer-Rh(C6H5PEt2)3Cl3

carbon dioxide