3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal

Base Information

Chemical Name:3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal
CAS No.:308796-41-0
Molecular Formula:C₁₉H₃₄O₆Si
Molecular Weight:386.561
Hs Code.:
DSSTox Substance ID:DTXSID10471262
Nikkaji Number:J1.955.603D
Wikidata:Q82299734
Mol file:308796-41-0.mol

Synonyms:308796-41-0;3,4-DI-O-ACETYL-6-O-TRIISOPROPYLSILYL-D-GLUCAL;3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal;[(2R,3S,4R)-3-acetyloxy-2-[tri(propan-2-yl)silyloxymethyl]-3,4-dihydro-2H-pyran-4-yl] acetate;DTXSID10471262;V10108;3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal, AldrichCPR

Suppliers and Price of 3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal Aldrich
1g
$ 186.00

Crysdot
3,4-DI-O-ACETYL-6-O-TRIISOPROPYLSILYL-D-GLUCAL 95+%
5g
$ 492.00

Chemenu
(2R,3S,4R)-2-(((Triisopropylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diyldiacetate 95%
5g
$ 465.00

American Custom Chemicals Corporation
3,4-DI-O-ACETYL-6-O-(TRIISOPROPYLSILYL)-D-GLUCAL 95.00%
250MG
$ 149.23

Total 2 raw suppliers

Chemical Property of 3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal

Chemical Property:

Refractive Index:n20/D 1.468(lit.)
Boiling Point:408.0±45.0 °C(Predicted)
Flash Point:>230 °F
PSA：71.06000
Density:1.042 g/mL at 25 °C(lit.)
LogP:4.73460
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:10
Exact Mass:386.21246533
Heavy Atom Count:26
Complexity:492

Purity/Quality:

99% ^*data from raw suppliers

3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal Aldrich ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)[Si](C(C)C)(C(C)C)OCC1C(C(C=CO1)OC(=O)C)OC(=O)C
Isomeric SMILES:CC(C)[Si](C(C)C)(C(C)C)OC[C@@H]1[C@H]([C@@H](C=CO1)OC(=O)C)OC(=O)C

Technology Process of 3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal

There total 3 articles about 3,4-Di-O-acetyl-6-O-(triisopropylsilyl)-D-glucal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 108-24-7
acetic anhydride

: 137915-37-8
1,2-dideoxy-6-O-triisopropylsilyl-D-arabino-1-hexenopyranose

: 308796-41-0
3,4-di-O-acetyl-6-O-triisopropylsilyl-D-glucal

Guidance literature:: With pyridine; dmap; In dichloromethane; at 20 ℃; for 3h;

Reference yield:

: 13265-84-4
D-glucal

: 308796-41-0
3,4-di-O-acetyl-6-O-triisopropylsilyl-D-glucal

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole

2: 80 percent / pyridine; DMAP / CH₂Cl₂ / 3 h / 20 °C

With pyridine; 1H-imidazole; dmap; In dichloromethane;

Reference yield:

: 2873-29-2
D-glucal triacetate

: 308796-41-0
3,4-di-O-acetyl-6-O-triisopropylsilyl-D-glucal

Guidance literature:: Multi-step reaction with 3 steps

1: NaOMe / methanol

2: imidazole

3: 80 percent / pyridine; DMAP / CH₂Cl₂ / 3 h / 20 °C

With pyridine; 1H-imidazole; dmap; sodium methylate; In methanol; dichloromethane;