Technology Process of Bromozinc(1+);pentane
There total 1 articles about Bromozinc(1+);pentane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
zinc;
With
lithium chloride;
for 0.5h;
Inert atmosphere;
With
ethylene dibromide;
In
tetrahydrofuran;
at 60 ℃;
for 0.333333h;
Inert atmosphere;
3-bromopentane;
Further stages;
DOI:10.1002/anie.201205747
DOI:10.1002/anie.201205747
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / tetrahydrofuran; 1,4-dioxane / 18 h / 75 °C
2.1: lithium hydroxide / methanol; water / 2 h / 20 °C
3.1: N-ethyl-N,N-diisopropylamine; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate / tetrahydrofuran; N,N-dimethyl-formamide / 0.17 h / 20 °C
3.2: 0.5 h / 20 °C
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine; lithium hydroxide;
In
tetrahydrofuran; 1,4-dioxane; methanol; water; N,N-dimethyl-formamide;
1.1: |Negishi Coupling;
DOI:10.1016/j.ejmech.2016.03.020
- Guidance literature:
-
Multi-step reaction with 2 steps
1: Pd-PEPPSI-IHeptCl / toluene / 18 h / 40 °C / Inert atmosphere; Schlenk technique
2: trifluoroacetic acid / 3 h / 70 °C / Inert atmosphere; Schlenk technique
With
trifluoroacetic acid;
In
toluene;
1: |Negishi Coupling;
