methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

Base Information

Chemical Name:methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside
CAS No.:228850-09-7
Molecular Formula:C₁₆H₁₉FO₆
Molecular Weight:326.322
Hs Code.:

Synonyms:methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

Suppliers and Price of methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 2 raw suppliers

Chemical Property of methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

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Technology Process of methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

There total 1 articles about methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: methyl 4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

: 108-24-7
acetic anhydride

: 228850-09-7
methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

Guidance literature:: With pyridine; dmap; at 0 - 20 ℃;
DOI:10.1016/j.carres.2006.08.024

Reference yield: 88.0%

: 228850-09-7
methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

: 228850-10-0
methyl 3-O-acetyl-4-O-benzoyl-6-bromo-2,6-dideoxy-2-fluoro-α-D-allopyranoside

Guidance literature:: With N-Bromosuccinimide; barium carbonate; In tetrachloromethane; for 2h; Heating;
DOI:10.1016/j.carres.2006.08.024

Reference yield:

: 228850-09-7
methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside

: 228850-12-2
methyl 3-O-acetyl-4-O-benzoyl-2,6-dideoxy-2-fluoro-β-L-talopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / NBS; BaCO₃ / CCl₄ / 2 h / Heating

2: 93 percent / DBU / benzene / 3 h / Heating

3: 88 percent / H₂ / Pd/BaSO₄ / ethyl acetate / 0.5 h

With N-Bromosuccinimide; hydrogen; 1,8-diazabicyclo[5.4.0]undec-7-ene; barium carbonate; Pd-BaSO₄; In tetrachloromethane; ethyl acetate; benzene;
DOI:10.1016/j.carres.2006.08.024