2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

Base Information

Chemical Name:2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester
CAS No.:794588-62-8
Molecular Formula:C₂₈H₃₄O₇
Molecular Weight:482.574
Hs Code.:

Synonyms:2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

Suppliers and Price of 2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

There total 3 articles about 2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 108-24-7
acetic anhydride

: 794588-46-8
2-allyl-6-hydroxybenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

: 794588-62-8
2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

Guidance literature:: With pyridine; dmap; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1016/j.tet.2004.06.146

Reference yield:

: 794588-45-7
1-allyloxy-5-(4-methoxybenzyloxy)pentan-3-ol

: 794588-62-8
2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisopropyl azodicarboxylate; PPh₃ / diethyl ether / 0 - 20 °C

1.2: 96 percent / K₂CO₃ / methanol

2.1: 95 percent / pyridine; DMAP / CH₂Cl₂ / 3 h / 20 °C

With pyridine; dmap; di-isopropyl azodicarboxylate; triphenylphosphine; In diethyl ether; dichloromethane; 1.1: Mitsunobu reaction;
DOI:10.1016/j.tet.2004.06.146

Reference yield:

: 794588-83-3
(S)-3-(tert-butyldimethylsilyloxy)-5-(4-methoxybenzyloxy)pentan-1-ol

: 794588-62-8
2-acetoxy-6-allylbenzoic acid 1-(2-allyloxyethyl)-3-(4-methoxybenzyloxy)propyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 78 percent / NaH / tetrahydrofuran / 20 h / 20 °C

2.1: 74 percent / TBAF / tetrahydrofuran / 5 h / 20 °C

3.1: diisopropyl azodicarboxylate; PPh₃ / diethyl ether / 0 - 20 °C

3.2: 96 percent / K₂CO₃ / methanol

4.1: 95 percent / pyridine; DMAP / CH₂Cl₂ / 3 h / 20 °C

With pyridine; dmap; di-isopropyl azodicarboxylate; tetrabutyl ammonium fluoride; sodium hydride; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; 3.1: Mitsunobu reaction;
DOI:10.1016/j.tet.2004.06.146