trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Base Information

Chemical Name:trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium
CAS No.:330680-47-2
Molecular Formula:C₂₁H₁₇Cl₃N₃O₆Ru
Molecular Weight:614.811
Hs Code.:

Synonyms:trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Suppliers and Price of trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

There total 4 articles about trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 10049-08-8,63767-78-2
ruthenium(III)chloride

: 330680-46-1
trimethyl 2,2:6′,2''-terpyridine-4,4',4''-tricarboxylate

: 330680-47-2
trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Guidance literature:: In ethanol; dichloromethane; under Ar mixt. RuCl3 and ethanol was stirred for 2 min, soln. ligand in CH2Cl2 was added and react. mixt. was refluxed for 2 h under Ar; soln. was concd., react. mixt. was cooled to room temp., ppt. was collected, washed with ethanol and air-dried; elem. anal.;
DOI:10.1021/ja003299u

Reference yield: 79.0%

: 14898-67-0
ruthenium trichloride hydrate

: 330680-46-1
trimethyl 2,2:6′,2''-terpyridine-4,4',4''-tricarboxylate

: 330680-47-2
trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Guidance literature:: In ethanol; dichloromethane; addn. of ligand in CH2Cl2 to RuCl3 in EtOH, refluxing 2 h, concn., pptn.; washing (EtOH)); elem. anal.;
DOI:10.1039/a703277c

Reference yield: 67.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 330680-46-1
trimethyl 2,2:6′,2''-terpyridine-4,4',4''-tricarboxylate

: 330680-47-2
trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Guidance literature:: In ethanol; RuCl3*3H2O and ligand in EtOH were refluxed for 8 h; soln. was cooled to room temp., ppt. was filtered and washed with water;
DOI:10.1021/ic300054j