dihydridobis(ethylene)bis(triphenylphosphine)iridium(III) tetrafluoroborate

Base Information

Chemical Name:dihydridobis(ethylene)bis(triphenylphosphine)iridium(III) tetrafluoroborate
CAS No.:83705-98-0
Molecular Formula:BF₄*C₄₀H₄₀IrP₂
Molecular Weight:861.73
Hs Code.:

Synonyms:dihydridobis(ethylene)bis(triphenylphosphine)iridium(III) tetrafluoroborate

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Chemical Property of dihydridobis(ethylene)bis(triphenylphosphine)iridium(III) tetrafluoroborate

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Technology Process of dihydridobis(ethylene)bis(triphenylphosphine)iridium(III) tetrafluoroborate

There total 2 articles about dihydridobis(ethylene)bis(triphenylphosphine)iridium(III) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 38834-40-1
[Ir(1,5-COD)(P(C₆H₅)3)2]BF₄

: 74-85-1
ethene

: 83705-98-0
dihydridobis(ethylene)bis(triphenylphosphine)iridium(III) tetrafluoroborate

Guidance literature:: With hydrogen; In dichloromethane-d2; byproducts: ethane; C2H4 (50 equiv) added to Ir-complex in CD2Cl2, cooled to ca. -80°C (dry ice), H2 added, excess H2 swept out with N2, warmed to 0°C;
DOI:10.1021/ja00389a018