5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

Base Information

Chemical Name:5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose
CAS No.:34311-63-2
Molecular Formula:C₁₅H₁₈O₅
Molecular Weight:278.305
Hs Code.:

Synonyms:5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

Suppliers and Price of 5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

There total 10 articles about 5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 23202-83-7,2592-42-9
5-benzyl-1,2-O-isopropylidene-α-D-xylofuranose

: 34311-63-2
5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 ℃; for 5h;
DOI:10.1021/jo200639t

Reference yield: 90.0%

: 100-39-0
benzyl bromide

: 20031-21-4
1,2-O-isopropylidene-α-D-xylose

: 34311-63-2
5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

Guidance literature:: benzyl bromide; 1,2-O-isopropylidene-α-D-xylose; With tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; at 90 ℃; Inert atmosphere;

With Dess-Martin periodane; In dichloromethane; at 20 ℃; Inert atmosphere;
DOI:10.1039/c9cc09093b

Reference yield:

: 20031-21-4
1,2-O-isopropylidene-α-D-xylose

: 34311-63-2
5-O-benzyl-3-oxo-1,2-O-isopropylidene-α-D-xylofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / (Bu₃Sn)2O; TBAB / toluene / 72 h / 90 °C

2: (COCl)2; DMSO; TEA

With oxalyl dichloride; TEA; tetrabutylammomium bromide; dimethyl sulfoxide; bis(tri-n-butyltin)oxide; In toluene; 2: Swern oxidation;
DOI:10.1016/j.tetlet.2003.11.001