Technology Process of C21H32O6
There total 8 articles about C21H32O6 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
pyridine; sulfur trioxide; triethylamine;
In
dimethyl sulfoxide;
DOI:10.1021/ol9909233
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 91 percent / DIBAL-H / CH2Cl2 / -78 - -10 °C
2: 93 percent / SO3; pyridine; Et3N / dimethylsulfoxide
With
pyridine; sulfur trioxide; diisobutylaluminium hydride; triethylamine;
In
dichloromethane; dimethyl sulfoxide;
2: Parikh-Doering oxidation;
DOI:10.1021/ol9909233
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: EtSLi
1.2: Et3SiH / Pd/C
2.1: Bu2BOTf; Et3N
2.2: LiBH4 / methanol
2.3: CSA
3.1: 93 percent / TBAF
4.1: 93 percent / NaH
5.1: 91 percent / DIBAL-H / CH2Cl2 / -78 - -10 °C
6.1: 93 percent / SO3; pyridine; Et3N / dimethylsulfoxide
With
pyridine; di-n-butylboryl trifluoromethanesulfonate; sulfur trioxide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; lithium thioethoxide; triethylamine;
In
dichloromethane; dimethyl sulfoxide;
2.1: Evans aldol condensation / 6.1: Parikh-Doering oxidation;
DOI:10.1021/ol9909233