5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone

Base Information

Chemical Name:5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone
CAS No.:1456722-79-4
Molecular Formula:C₈₂H₆₈N₈O₄
Molecular Weight:1229.49
Hs Code.:

Synonyms:5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone

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Chemical Property of 5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone

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Technology Process of 5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone

There total 2 articles about 5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 381218-99-1
4′-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-2,2′,6′,2″-terpyridine

: 209111-67-1
N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide)

: 1456722-79-4
5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone

Guidance literature:: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; tetrabutyl-ammonium chloride; potassium carbonate; In water; toluene; at 90 ℃; for 18h;
DOI:10.1002/chem.201503738

Reference yield: 31.0%

: 381218-96-8
4′-(4-boronatophenyl)-2,2′:6′,2′′-terpyridine

: 209111-67-1
N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide)

: 1456722-79-4
5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; In water; toluene; tert-butyl alcohol; at 100 ℃; Inert atmosphere;
DOI:10.3987/COM-14-S(K)49

Reference yield: 78.0%

: ammonium hexafluorophosphate

: 136276-24-9
[trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]

: 1456722-79-4
5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone

: C₁₂₆H₁₀₂N₁₄O₄Ru₂⁽⁴⁺⁾*4F₆P^(1-)

Guidance literature:: [trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]; 5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone; With N-ethylmorpholine;; In ethanol; chloroform; for 12h; Reflux;

ammonium hexafluorophosphate;
DOI:10.3987/COM-14-S(K)49