N,N'-di-(n-octyl)-1,7-dibroMoperylene-3,4:9,10-tetracarboxylic acid bisiMide

Base Information

• Chemical Name: N,N'-di-(n-octyl)-1,7-dibroMoperylene-3,4:9,10-tetracarboxylic acid bisiMide
• CAS No.: 209111-67-1
• Molecular Formula: C₄₀H₄₀Br₂N₂O₄
• Molecular Weight: 772.577
• Mol file: 209111-67-1.mol

Synonyms:N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide)

Chemical Property of N,N'-di-(n-octyl)-1,7-dibroMoperylene-3,4:9,10-tetracarboxylic acid bisiMide

Chemical Property:

• Boiling Point: 841.6±65.0 °C(Predicted)
• PKA: -2.79±0.20(Predicted)
• Density: 1.463±0.06 g/cm3(Predicted)
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

≥99% ^*data from raw suppliers

5,12-Dibromo-2,9-dioctylanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-di-(n-octyl)-1,7-dibroMoperylene-3,4:9,10-tetracarboxylic acid bisiMide

There total 7 articles about N,N'-di-(n-octyl)-1,7-dibroMoperylene-3,4:9,10-tetracarboxylic acid bisiMide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

n-Octylamine (111-86-4) + 1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride (118129-60-5) → N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide) (209111-67-1)

Guidance literature:

In 1-methyl-pyrrolidin-2-one; at 80 ℃; for 10h; Inert atmosphere;

DOI:10.1039/C6RA27003D

Reference yield: 1.0%

n-Octylamine (111-86-4) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → 1,6-dibromo-N,N'-di(2-ethylhexyl)-perylene-3,4,9,10-tetracarboxydiimide + 1,6,7-tribromo-N,N'-di(2-ethylhexyl)-perylene-3,4,9,10-tetracarboxydiimide (1246811-21-1) + N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide) (209111-67-1)

Guidance literature:

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride; With sulfuric acid; bromine; iodine; at 85 ℃; for 24h;

n-Octylamine; With propionic acid; for 48h; Reflux;

DOI:10.1021/cm1018647

Reference yield:

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide) (209111-67-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / Br₂, H₂SO₄ / 12 h / 40 °C

2: CH₃COOH / various solvent(s) / 8 h / 85 °C

With sulfuric acid; bromine; acetic acid; In various solvent(s);

DOI:10.1002/(SICI)1521-3773(19980605)37:10<1434::AID-ANIE1434>3.0.CO;2-P

upstream raw materials:

n-Octylamine

1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

N,N'-di(n-octyl)perylene-3,4:9,10-bis(dicarboximide)

Downstream raw materials:

1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide

1,7-bis(3,5-di-tert-butylphenyl)-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide

N,N′‐dioctyl‐1,7‐di (4‐tert‐butylphenoxy)perylene‐3,4;9,10‐tetracarboxydiimide

5,12-bis(4-([2,2′:6′,2″-terpyridin]-4′-yl)phenyl)-2,9-dioctylanthra[2,1,9-def:6,5,10-d′e′f ′]diisoquinoline-1,3,8,10(2H,9H)tetraone