(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

Base Information

Chemical Name:(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate
CAS No.:36874-87-0
Molecular Formula:C₂₀H₂₃ClO₉S
Molecular Weight:474.916
Hs Code.:

Synonyms:(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

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Chemical Property of (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

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Technology Process of (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

There total 7 articles about (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 106-54-7
p-Chlorothiophenol

: 604-69-3
β-D-glucose pentaacetate

: 36874-87-0
(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

Guidance literature:: With indium(III) bromide; In dichloromethane; at 20 ℃; for 2h; stereoselective reaction;
DOI:10.1055/s-0036-1588507

Reference yield: 87.0%

: 106-39-8
bromochlorobenzene

: 19879-84-6
tetraacetyl thioglucose

: 36874-87-0
(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

Guidance literature:: With 4,4'-di-tert-butyl-2,2'-bipyridine; lithium bromide; nickel dibromide; In N,N-dimethyl-formamide; at 20 ℃; for 3h; Electrochemical reaction; Inert atmosphere;
DOI:10.1039/d0cc01126f

Reference yield: 86.0%

: 1142-19-4
4,4'-dichlorodiphenyl disulfide

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 36874-87-0
(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-chlorophenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate

Guidance literature:: 4,4'-dichlorodiphenyl disulfide; With rongalite; potassium carbonate; In N,N-dimethyl-formamide; at 25 ℃; for 0.166667h;

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide; In N,N-dimethyl-formamide; at 25 ℃; for 1h;
DOI:10.1016/j.carres.2014.07.011