ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate

Base Information

Chemical Name:ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate
CAS No.:1011458-53-9
Molecular Formula:C₁₉H₁₉ClO₄S
Molecular Weight:378.876
Hs Code.:

Synonyms:ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate

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Chemical Property of ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate

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Technology Process of ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate

There total 3 articles about ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 7605-25-6
ethyl phenylsulfenylacetate

: 93961-29-6
methyl 2-(4-chlorophenyl)-2-diazoacetate

: 1011458-53-9
ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate

Guidance literature:: With rhodium(II) trifluoroacetate dimer; In toluene; at 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/ol703058p

Reference yield:

: 108-98-5
thiophenol

: 1011458-53-9
ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine / tetrahydrofuran / 4 h / 20 °C

2: dichloromethane / 25 °C / Irradiation

With triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1002/chem.201900597

Reference yield:

: 52449-43-1
(4-chloro-phenyl)-acetic acid methyl ester

: 1011458-53-9
ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate

Guidance literature:: Multi-step reaction with 2 steps

1: 4-toluenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 20 °C

2: dichloromethane / 25 °C / Irradiation

With 4-toluenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; acetonitrile;
DOI:10.1002/chem.201900597