93961-29-6

Basic information

• Product Name: methyl 2-(4-chlorophenyl)-2-diazoacetate
• Synonyms: methyl 2-(4-chlorophenyl)-2-diazoacetate
• CAS NO: 93961-29-6
• Molecular Weight: 210.62
• Mol File: 93961-29-6.mol
• Article Data: 58

Chemical Properties

• CAS DataBase Reference: methyl 2-(4-chlorophenyl)-2-diazoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(4-chlorophenyl)-2-diazoacetate(93961-29-6)
• EPA Substance Registry System: methyl 2-(4-chlorophenyl)-2-diazoacetate(93961-29-6)

Safety Data

• Hazardous Substances Data: 93961-29-6(Hazardous Substances Data)

Upstream product

• 52449-43-1 (4-chloro-phenyl)-acetic acid methyl ester 
• 37542-28-2 methyl (p-chlorphenyl)glyoxylate 
• 1878-66-6 4-chlorophenylacetic Acid 
• 941-55-9 4-toluenesulfonyl azide 
• 2158-14-7 4-acetamidobenzenesulfonyl azide 

Downstream Products

• 1011458-53-9 ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate 
• 1206707-18-7 methyl 2-(4-chlorophenyl)-2-(1H-indol-2-yl)acetate 
• 1394823-40-5 methyl 2-((2,2-dimethoxyethyl)amino)-2-(4-chlorophenyl)acetate 
• 1616346-46-3 methyl 1-(4-chlorophenyl)-3-oxo-2,3-dihydro-1H-imidazo[1,5-a]indole-1-carboxylate 
• 1616346-53-2 methyl 1-(4-chlorophenyl)-7-methoxy-3-oxo-2,3-dihydro-1H-imidazo[1,5-a]indole-1-carboxylate 

Relevant articles and documents

All-Carbon Tetrasubstituted Olefins Synthesis from Diazo Compounds and Iodonium Ylides under Blue LED Irradiation

A route for the construction of all-carbon tetra-substituted olefins through visible-light promoted coupling of diazo compounds with iodonium ylides was developed. A wide range of all-carbon tetra-substituted olefins was obtained in moderate to good yields. The synthetic values of the current method were further approved by the synthesis of natural isolates modified alkenes and the successful transformation of final olefins into important heterocycles. (Figure presented.).

Catalyst-free, scalable heterocyclic flow photocyclopropanation

Industrial process development is driven by several factors, including safety, cost, robustness and environmental aspects. However, attempts to establish aryl diazo esters-which are highly valued in academic research for their reactivity as carbene precur

Tropylium-Catalyzed O-H Insertion Reactions of Diazoalkanes with Carboxylic Acids

Herein, we describe the application of a nonbenzenoid aromatic carbocation, namely tropylium, as an organic Lewis acid catalyst in O-H functionalization reactions of diazoalkanes with benzoic acids. The newly developed protocol is applicable to a wide range of diazoalkane and carboxylic acid substrates with excellent efficiency (43 examples, up to 99% yield).