[(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2]Pt[OCH(CH₃)2]2

Base Information

• Chemical Name: [(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2]Pt[OCH(CH₃)2]2
• CAS No.: 156053-79-1
• Molecular Formula: C₃₃H₄₀O₂P₂Pt
• Molecular Weight: 725.707
• Mol file: 156053-79-1.mol

Synonyms:[(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2]Pt[OCH(CH₃)2]2

Chemical Property of [(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2]Pt[OCH(CH₃)2]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2]Pt[OCH(CH₃)2]2

There total 1 articles about [(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2]Pt[OCH(CH₃)2]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) + sodium isopropylate (683-60-3) → [(C6H5)2PCH2CH2CH2P(C6H5)2]Pt[OCH(CH3)2]2 (156053-79-1)

Guidance literature:

In tetrahydrofuran; under Ar; to suspn. of Pt-complex/THF was added NaOCH(CH3)2 in aliquotsover 5-10 min with stirring, stirred 3 h; filtered, not isolated, detected by 31P-NMR;

DOI:10.1021/ja00092a025

Reference yield:

[(C6H5)2PCH2CH2CH2P(C6H5)2]Pt[OCH(CH3)2]2 (156053-79-1) → (1,3-bis(diphenylphosphino)propane)Pt(CO3) (156053-80-4)

Guidance literature:

With CO₂; In tetrahydrofuran; water; under Ar; to soln. Pt-complex/THF (prepared in situ from (dppp)PtCl2 and NaOCH(CH3)2) with added NaCl (to facilitate crystn.) was added water (5 equiv/Pt), soln. stirred, CO2 bubbled through, copious white ppt. within 1 min, stirred 30 min under CO2; centrifuged, washed in air (ether), dried (vac.), dissolved in CH2Cl2, hexane diffused in over 2 d, white powder washed (CH2Cl2/hexane (1:1)), dried (vac.), treatment of mother liquor with hexane gave additional product, elem. anal.;

DOI:10.1021/ja00092a025

Reference yield:

[(C6H5)2PCH2CH2CH2P(C6H5)2]Pt[OCH(CH3)2]2 (156053-79-1) → [(1,3-bis(diphenylphosphino)propane)]platinum(II)(1,2-propanediolate) (156053-58-6)

Guidance literature:

Multi-step reaction with 2 steps

1: CO₂ / tetrahydrofuran; water

2: dichloromethane

With CO₂; In tetrahydrofuran; dichloromethane; water;

DOI:10.1021/ja00092a025

upstream raw materials:

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

sodium isopropylate

Downstream raw materials:

(1,3-bis(diphenylphosphino)propane)Pt(CO₃)

[(1,3-bis(diphenylphosphino)propane)]platinum(II)(1,2,4-butanetriolate)

[(1,3-bis(diphenylphosphino)propane)]platinum(II)(1,2-ethanediolate)

[(1,3-bis(diphenylphosphino)propane)]platinum(II)(3-methoxy-2,3-propanediolate)