5-Allylbicyclo[2.2.1]hept-2-ene

Base Information

• Chemical Name: 5-Allylbicyclo[2.2.1]hept-2-ene
• CAS No.: 31663-53-3
• Molecular Formula: C₁₀H₁₄
• Molecular Weight: 134.221
• Hs Code.: 2902199090
• Mol file: 31663-53-3.mol

Synonyms:2-Norbornene,5-allyl- (8CI); Bicyclo[2.2.1]hept-2-ene, 5-(2-propenyl)- (9CI);2-Allylbicyclo[2.2.1]hept-5-ene

Chemical Property of 5-Allylbicyclo[2.2.1]hept-2-ene

Chemical Property:

• Vapor Pressure: 2.01mmHg at 25°C
• Refractive Index: 1.502
• Boiling Point: 169.8°C at 760 mmHg
• Flash Point: 39.7°C
• PSA: 0.00000
• Density: 0.908g/cm³
• LogP: 2.77470

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-Allylbicyclo[2.2.1]hept-2-ene

There total 3 articles about 5-Allylbicyclo[2.2.1]hept-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-formyloxy-propene (1838-59-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → 5-allylbicyclo[2.2.1]hept-2-ene (31663-53-3) + 8-methylenetetracyclo<4.3.0.02,4.03,7>nonane (55053-96-8)

Guidance literature:

With palladium (II) acetate; In acetonitrile; at 25 ℃; for 48h; Inert atmosphere;

DOI:10.1007/s11172-016-1629-z

Reference yield:

3-formyloxy-propene (1838-59-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → 5-allylbicyclo[2.2.1]hept-2-ene (31663-53-3) + (1R,4S,6R)-5-Methylene-6-vinyl-bicyclo[2.2.1]hept-2-ene (110919-83-0,137105-19-2,137105-20-5) + (1R,2R,5S,6S)-3-Methylene-tricyclo[4.2.1.02,5]non-7-ene (110919-82-9,113349-97-6,137172-42-0) + 8-methylenetetracyclo<4.3.0.02,4.03,7>nonane (55053-96-8)

Guidance literature:

With palladium (II) acetate; triphenylphosphine; In acetonitrile; at 25 ℃; for 48h; Inert atmosphere;

DOI:10.1007/s11172-016-1629-z

Reference yield:

3-formyloxy-propene (1838-59-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → 5-allylbicyclo[2.2.1]hept-2-ene (31663-53-3) + (1R,4S,6R)-5-Methylene-6-vinyl-bicyclo[2.2.1]hept-2-ene (110919-83-0,137105-19-2,137105-20-5) + (1R,2R,5S,6S)-3-Methylene-tricyclo[4.2.1.02,5]non-7-ene (110919-82-9,113349-97-6,137172-42-0) + 8-methylenetetracyclo<4.3.0.02,4.03,7>nonane (55053-96-8) + exo-3-Methyl-tricyclo<4.2.1.02,5>nona-3,7-dien

Guidance literature:

With palladium (II) acetate; triphenylphosphine; In acetonitrile; at 25 ℃; for 48h; Inert atmosphere;

DOI:10.1007/s11172-016-1629-z

upstream raw materials:

3-formyloxy-propene

bicyclo[2.2.1]hepta-2,5-diene