[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]ClO₄

Base Information

• Chemical Name: [Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]ClO₄
• CAS No.: 84190-87-4
• Molecular Formula: C₅₀H₅₄O₂P₂Rh*ClO₄
• Molecular Weight: 951.281

Synonyms:[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]ClO₄

Chemical Property of [Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]ClO₄

There total 1 articles about [Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + tri(4-methylphenyl)phosphine oxide (797-70-6) + silver perchlorate → [Rh((CHCHC2H4)2)(OP(CH3C6H4)3)2](1+)*ClO4(1-)=[Rh((CHCHC2H4)2)(OP(CH3C6H4)3)2]ClO4 (84190-87-4)

Guidance literature:

In acetone; byproducts: AgCl; complex treated with AgClO4 in acetone, filtered, ligand added at room temp.; evapd. (vac.), suspended in hexane, filtered off, washed with hexane, air-dried; elem. anal.;

DOI:10.1016/S0022-328X(00)85856-8

Reference yield: 90.0%

[Rh((CHCHC2H4)2)(OP(CH3C6H4)3)2](1+)*ClO4(1-)=[Rh((CHCHC2H4)2)(OP(CH3C6H4)3)2]ClO4 (84190-87-4) → [Rh(CO)(OP(CH3C6H4)3)(P(C6H5)3)2](1+)*ClO4(1-)=[Rh(CO)(OP(CH3C6H4)3)(P(C6H5)3)2]ClO4 (84190-63-6)

Guidance literature:

With CO; PPh₃; In dichloromethane; CO bubbled through complex soln. at room temp., PPh3 added, stirred for30 min; evapd., suspended in hexane, filtered off, washed with hexane, dried (vac.); elem. anal.;

DOI:10.1016/S0022-328X(00)85856-8

Reference yield:

[Rh((CHCHC2H4)2)(OP(CH3C6H4)3)2](1+)*ClO4(1-)=[Rh((CHCHC2H4)2)(OP(CH3C6H4)3)2]ClO4 (84190-87-4) → [Rh(CO)2(OP(CH3C6H4)3)2](1+)*ClO4(1-)=[Rh(CO)2(OP(CH3C6H4)3)2]ClO4 (84191-05-9)

Guidance literature:

With CO; In dichloromethane; CO bubbled at room temp. for 15 min; ether added with CO bubbling, not isolated, detected by IR;

DOI:10.1016/S0022-328X(00)85856-8

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

tri(4-methylphenyl)phosphine oxide

Downstream raw materials:

[Rh(CO)(OP(CH₃C₆H₄)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(OP(CH₃C₆H₄)3)(P(C₆H₅)3)2]ClO₄

[Rh(CO)2(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)2(OP(CH₃C₆H₄)3)2]ClO₄

[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)(P(C₆H₅)3)]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)(P(C₆H₅)3)]ClO₄

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 84190-87-4 [Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CHCHC₂H₄)2)(OP(CH₃C₆H₄)3)2]ClO₄

Send

Send

Metric Ton KG G Pound L ML

Send

Send