{hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh

Base Information

• Chemical Name: {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh
• CAS No.: 129238-84-2
• Molecular Formula: C₂₁H₂₇BMoN₆O₃
• Molecular Weight: 518.235
• Mol file: 129238-84-2.mol

Synonyms:{hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh

Chemical Property of {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh

There total 3 articles about {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

{hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)Br + phenol (108-95-2,27073-41-2) → {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh (129238-84-2)

Guidance literature:

With NEt₃; In not given; N2-atmosphere; stirring Mo-complex with 4 equiv. of phenol and Et3N (indichloroethane, 70°C, 5 h); concn., chromy. (silica gel, MePh), recrystn. (CH2Cl2/MeOH);

DOI:10.1021/ic00128a005

Reference yield: 71.0%

{hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)Cl → {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh (129238-84-2)

Guidance literature:

With (C₂H₅)3N; C₆H₅OH; In toluene; (N2), stirred at 70°C overnight; filtered, evapd. to dryness, chromy. (silica gel, toluene), evapd. to dryness, elem. anal.;

Reference yield:

potassium hydridotris(3,5-dimethylpyrazolyl)borate (17567-17-8) → {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)OPh (129238-84-2)

Guidance literature:

Multi-step reaction with 2 steps

1: N,N-dimethyl-formamide

2: (C₂H₅)3N; C₆H₅OH / toluene

With (C₂H₅)3N; C₆H₅OH; In N,N-dimethyl-formamide; toluene;

upstream raw materials:

phenol

potassium hydridotris(3,5-dimethylpyrazolyl)borate

Downstream raw materials:

{hydrotris(3,5-dimethyl-1-pyrazolyl)borate}oxomolybdenum(IV)(OPh)(DMF)

{hydrotris(3,5-dimethyl-1-pyrazolyl)borate}oxomolybdenum(V)(Cl)(OPh)