(E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester

Base Information

Chemical Name:(E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester
CAS No.:331625-57-1
Molecular Formula:C₄₆H₆₄O₁₀
Molecular Weight:777.008
Hs Code.:

Synonyms:(E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester

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Chemical Property of (E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester

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Technology Process of (E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester

There total 9 articles about (E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 532-20-7,613-83-2,7261-25-8,7687-39-0,13221-22-2,14795-83-6,15761-67-8,20074-49-1,25545-03-3,25545-04-4,32445-75-3,34436-17-4,36441-93-7,36468-53-8,37110-85-3,37388-49-1,38029-69-5,40461-77-6,40461-89-0,41546-19-4,41546-20-7,41546-21-8,41546-26-3,41546-29-6,41546-30-9,41546-31-0,126872-16-0,131064-98-7
D-Ribose

: 331625-57-1
(E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester

Guidance literature:: Multi-step reaction with 9 steps

1: H₂SO₄ / 12 h / 4 °C

2: 4.49 g / Bu₄NBr; KOH / tetrahydrofuran; H₂O / 5 h / 90 °C

3: 87 percent / DIBAL; [1,3-bis(diphenylphosphino)propane]dichloronickel(II) / diethyl ether; hexane / 6 h / 20 °C

4: 94 percent / Et₃N / CH₂Cl₂ / 15 h / 20 °C

5: 84 percent / DCC; DMAP / CH₂Cl₂ / 2.5 h / Heating

6: 69 percent / formic acid / diethyl ether / 12 h / 20 °C

7: tetra-n-propylammonium perruthenate; NMO / CH₂Cl₂ / 1 h / 20 °C

8: NaClO₂; sodium dihydrogenphosphate dihydrate; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 6 h / 20 °C

9: 54 mg / tetrahydrofuran; methanol; hexane / 0.08 h / 20 °C

With dmap; potassium hydroxide; sodium chlorite; sodium dihydrogenphosphate; formic acid; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 2-methyl-but-2-ene; [1,3-bis(diphenylphosphino)propane]dichloronickel(II); sulfuric acid; tetrabutylammomium bromide; diisobutylaluminium hydride; triethylamine; dicyclohexyl-carbodiimide; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; water; tert-butyl alcohol;
DOI:10.1021/ja0057272

Reference yield:

: 541546-94-5,773896-71-2
allyl α,β-D-ribofuranoside

: 331625-57-1
(E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 4.49 g / Bu₄NBr; KOH / tetrahydrofuran; H₂O / 5 h / 90 °C

2: 87 percent / DIBAL; [1,3-bis(diphenylphosphino)propane]dichloronickel(II) / diethyl ether; hexane / 6 h / 20 °C

3: 94 percent / Et₃N / CH₂Cl₂ / 15 h / 20 °C

4: 84 percent / DCC; DMAP / CH₂Cl₂ / 2.5 h / Heating

5: 69 percent / formic acid / diethyl ether / 12 h / 20 °C

6: tetra-n-propylammonium perruthenate; NMO / CH₂Cl₂ / 1 h / 20 °C

7: NaClO₂; sodium dihydrogenphosphate dihydrate; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 6 h / 20 °C

8: 54 mg / tetrahydrofuran; methanol; hexane / 0.08 h / 20 °C

With dmap; potassium hydroxide; sodium chlorite; sodium dihydrogenphosphate; formic acid; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 2-methyl-but-2-ene; [1,3-bis(diphenylphosphino)propane]dichloronickel(II); tetrabutylammomium bromide; diisobutylaluminium hydride; triethylamine; dicyclohexyl-carbodiimide; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; water; tert-butyl alcohol;
DOI:10.1021/ja0057272

Reference yield:

: 331625-80-0
(2S,3R,4R)-2,3,5-tris(4-methoxybenzyloxy)-1,4-pentanediol

: 331625-57-1
(E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 94 percent / Et₃N / CH₂Cl₂ / 15 h / 20 °C

2: 84 percent / DCC; DMAP / CH₂Cl₂ / 2.5 h / Heating

3: 69 percent / formic acid / diethyl ether / 12 h / 20 °C

4: tetra-n-propylammonium perruthenate; NMO / CH₂Cl₂ / 1 h / 20 °C

5: NaClO₂; sodium dihydrogenphosphate dihydrate; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 6 h / 20 °C

6: 54 mg / tetrahydrofuran; methanol; hexane / 0.08 h / 20 °C

With dmap; sodium chlorite; sodium dihydrogenphosphate; formic acid; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 2-methyl-but-2-ene; triethylamine; dicyclohexyl-carbodiimide; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; water; tert-butyl alcohol;
DOI:10.1021/ja0057272