C₆₂H₁₀₀O₁₄Si

Base Information

Chemical Name:C₆₂H₁₀₀O₁₄Si
CAS No.:206255-55-2
Molecular Formula:C₆₂H₁₀₀O₁₄Si
Molecular Weight:1097.55
Hs Code.:

C<sub>62</sub>H<sub>100</sub>O<sub>14</sub>Si

Synonyms:C₆₂H₁₀₀O₁₄Si

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Chemical Property of C₆₂H₁₀₀O₁₄Si

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Technology Process of C₆₂H₁₀₀O₁₄Si

There total 18 articles about C₆₂H₁₀₀O₁₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 206255-40-5
6-(tert-Butyl-dimethyl-silanyloxy)-5,5-dimethyl-hexane-2,4-dione

: 206255-55-2
C₆₂H₁₀₀O₁₄Si

Guidance literature:: Multi-step reaction with 17 steps

1: 1.) LDA, 3.) p-TsOH

2: NaBH₄, CeCl₃*7H₂O / methanol / -20 °C

3: m-CPBA, NaHCO₃ / CH₂Cl₂

4: DMAP / CH₂Cl₂ / -10 °C

5: Dess-Martin periodinane / Ambient temperature

6: 95 percent / SmI₂ / tetrahydrofuran; methanol / -78 °C

7: 90 percent / LDA / tetrahydrofuran / -78 °C

8: Et₃N / CH₂Cl₂ / -10 °C

9: DBU / tetrahydrofuran / Ambient temperature

10: NaBH₄, CeCl₃*7H₂O / methanol / -20 °C

11: 2,4,6-trichlorobenzoyl chloride, Et₃N / toluene / Ambient temperature

12: HF, pyridine / tetrahydrofuran / Ambient temperature

13: Dess-Martin periodinane / CH₂Cl₂ / Ambient temperature

14: 2.) Ac₂O, DMAP, 3.) OsO₄, NMO, 4.) Pb(OAc)4, Et₃N, 5.) DBU

15: 79 percent / DDQ / CH₂Cl₂; H₂O

16: 95 percent / aq. HF / acetonitrile / Ambient temperature

17: 1.) 2,4,6-trichlorobenzoyl chloride, Et₃N, 2.) DMAP / 1.) toluene, RT, 2.) toluene

With pyridine; lead(IV) acetate; dmap; sodium tetrahydroborate; osmium(VIII) oxide; N-methyl-2-indolinone; samarium diiodide; cerium(III) chloride; 2,4,6-trichlorobenzoyl chloride; hydrogen fluoride; acetic anhydride; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/ja9727631

Reference yield:

: 206255-41-6
(3R,4R)-4-Benzyloxy-3-(4-methoxy-benzyloxy)-pentanal

: 206255-55-2
C₆₂H₁₀₀O₁₄Si

Guidance literature:: Multi-step reaction with 17 steps

1: 1.) LDA, 3.) p-TsOH

2: NaBH₄, CeCl₃*7H₂O / methanol / -20 °C

3: m-CPBA, NaHCO₃ / CH₂Cl₂

4: DMAP / CH₂Cl₂ / -10 °C

5: Dess-Martin periodinane / Ambient temperature

6: 95 percent / SmI₂ / tetrahydrofuran; methanol / -78 °C

7: 90 percent / LDA / tetrahydrofuran / -78 °C

8: Et₃N / CH₂Cl₂ / -10 °C

9: DBU / tetrahydrofuran / Ambient temperature

10: NaBH₄, CeCl₃*7H₂O / methanol / -20 °C

11: 2,4,6-trichlorobenzoyl chloride, Et₃N / toluene / Ambient temperature

12: HF, pyridine / tetrahydrofuran / Ambient temperature

13: Dess-Martin periodinane / CH₂Cl₂ / Ambient temperature

14: 2.) Ac₂O, DMAP, 3.) OsO₄, NMO, 4.) Pb(OAc)4, Et₃N, 5.) DBU

15: 79 percent / DDQ / CH₂Cl₂; H₂O

16: 95 percent / aq. HF / acetonitrile / Ambient temperature

17: 1.) 2,4,6-trichlorobenzoyl chloride, Et₃N, 2.) DMAP / 1.) toluene, RT, 2.) toluene

With pyridine; lead(IV) acetate; dmap; sodium tetrahydroborate; osmium(VIII) oxide; N-methyl-2-indolinone; samarium diiodide; cerium(III) chloride; 2,4,6-trichlorobenzoyl chloride; hydrogen fluoride; acetic anhydride; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/ja9727631

Reference yield:

: (2S,4S)-2-[(2R,3R)-3-Benzyloxy-2-(4-methoxy-benzyloxy)-butyl]-6-[2-(tert-butyl-dimethyl-silanyloxy)-1,1-dimethyl-ethyl]-3,4-dihydro-2H-pyran-4-ol

: 206255-55-2
C₆₂H₁₀₀O₁₄Si

Guidance literature:: Multi-step reaction with 15 steps

1: m-CPBA, NaHCO₃ / CH₂Cl₂

2: DMAP / CH₂Cl₂ / -10 °C

3: Dess-Martin periodinane / Ambient temperature

4: 95 percent / SmI₂ / tetrahydrofuran; methanol / -78 °C

5: 90 percent / LDA / tetrahydrofuran / -78 °C

6: Et₃N / CH₂Cl₂ / -10 °C

7: DBU / tetrahydrofuran / Ambient temperature

8: NaBH₄, CeCl₃*7H₂O / methanol / -20 °C

9: 2,4,6-trichlorobenzoyl chloride, Et₃N / toluene / Ambient temperature

10: HF, pyridine / tetrahydrofuran / Ambient temperature

11: Dess-Martin periodinane / CH₂Cl₂ / Ambient temperature

12: 2.) Ac₂O, DMAP, 3.) OsO₄, NMO, 4.) Pb(OAc)4, Et₃N, 5.) DBU

13: 79 percent / DDQ / CH₂Cl₂; H₂O

14: 95 percent / aq. HF / acetonitrile / Ambient temperature

15: 1.) 2,4,6-trichlorobenzoyl chloride, Et₃N, 2.) DMAP / 1.) toluene, RT, 2.) toluene

With pyridine; lead(IV) acetate; dmap; sodium tetrahydroborate; osmium(VIII) oxide; N-methyl-2-indolinone; samarium diiodide; cerium(III) chloride; 2,4,6-trichlorobenzoyl chloride; hydrogen fluoride; acetic anhydride; sodium hydrogencarbonate; Dess-Martin periodane; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/ja9727631