{RuH(B₃H₈)(CO)(P(C₆H₅)3)2}

Base Information

• Chemical Name: {RuH(B₃H₈)(CO)(P(C₆H₅)3)2}
• CAS No.: 102532-12-7
• Molecular Formula: C₃₇H₃₉B₃OP₂Ru
• Molecular Weight: 695.167
• Mol file: 102532-12-7.mol

Synonyms:{RuH(B₃H₈)(CO)(P(C₆H₅)3)2}

Chemical Property of {RuH(B₃H₈)(CO)(P(C₆H₅)3)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {RuH(B₃H₈)(CO)(P(C₆H₅)3)2}

There total 2 articles about {RuH(B₃H₈)(CO)(P(C₆H₅)3)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

{ruthenium(II)(CO)H(meCN)2(PPh3)2}ClO4 (35798-09-5) + tetramethylammonium octahydrotriborate → {RuH(B3H8)(CO)(P(C6H5)3)2} (102532-12-7)

Guidance literature:

In dichloromethane; treating of a soln. of the Ru complex in CH2Cl2 with (NMe4)(B3H8), stirring for 10 h under N2; addn. of hexane, filtration, concn. of the filtrate, filtration, recrystn. from CH2Cl2/ethanol, elem. anal.;

Reference yield: 71.0%

Ru(Ph)Cl(CO)(triphenylphosphine)2 + tetrabutylammonium octahydrotriborate → {RuH(B3H8)(CO)(P(C6H5)3)2} (102532-12-7) + Ru(C6H5)(B3H8)(CO)(P(C6H5)3)2

Guidance literature:

In dichloromethane; (N2, Schlenk) a soln. of Ru-complex in CH2Cl2 was treated with solid B-compound, the mixt. was stirred for 30 min; ethanol was added, slow reduced in vol. under reduced pressure, the brown solid was filtered, the filtrate was concd., twice recrystd. from mixt. of CH2Cl2 and ethanol; elem. anal.;

DOI:10.1021/om100557q

Reference yield: 84.0%

N-iodo-succinimide (516-12-1) + {RuH(B3H8)(CO)(P(C6H5)3)2} (102532-12-7) → {RuI(B3H8)(CO)(P(C6H5)3)2} (141216-58-2)

Guidance literature:

In dichloromethane; byproducts: succinimide; stirring of a soln. of the Ru complex and N-bromosuccinimide in CH2Cl2 for 1 h under N2; removing the solvent under reduced pressure, crystn. from CH2Cl2/ethanol;

upstream raw materials:

{ruthenium(II)(CO)H(meCN)2(PPh₃)2}ClO₄

Downstream raw materials:

{RuCl(B₃H₈)(CO)(P(C₆H₅)3)2}

{RuI(B₃H₈)(CO)(P(C₆H₅)3)2}

{RuHCl(CNC(CH₃)3)2(P(C₆H₅)3)2}

{RuBr(B₃H₈)(CO)(P(C₆H₅)3)2}