Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

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Chemical Name:Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester
CAS No.:140888-89-7
Molecular Formula:C₂₂H₄₅O₈PS
Molecular Weight:500.634
Hs Code.:

Synonyms:Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

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Chemical Property of Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

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Technology Process of Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

There total 4 articles about Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 143570-25-6
Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

: 140888-89-7
Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

Guidance literature:: With boron trifluoride diethyl etherate; ethanethiol; In chloroform;
DOI:10.1016/S0040-4039(00)74812-X

Reference yield:

: 2917-26-2
16-mercaptohexadecanoate

: 140888-89-7
Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1) n-BuLi / 1) THF, 0 deg C, 30 min, 2) room temp., 1 h

2: CH₂Cl₂ / 6 h / Ambient temperature

3: triisopropylbenzensulfonyl chloride (TPSCl), Et₃N, pyridine / 24 h / Ambient temperature

4: 98 percent / BF₃*Et₂O, EtSH / CHCl₃

With pyridine; n-butyllithium; triisopropylbenzensulfonyl chloride; boron trifluoride diethyl etherate; triethylamine; ethanethiol; In dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)74812-X

Reference yield:

: 143570-23-4
Thiophosphoric acid O,O'-diethyl ester S-hexadecyl ester

: 140888-89-7
Thiophosphoric acid S-hexadecyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 3 steps

1: CH₂Cl₂ / 6 h / Ambient temperature

2: triisopropylbenzensulfonyl chloride (TPSCl), Et₃N, pyridine / 24 h / Ambient temperature

3: 98 percent / BF₃*Et₂O, EtSH / CHCl₃

With pyridine; triisopropylbenzensulfonyl chloride; boron trifluoride diethyl etherate; triethylamine; ethanethiol; In dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)74812-X