5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal

Base Information

Chemical Name:5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal
CAS No.:913193-93-8
Molecular Formula:C₃₅H₅₀O₄Si₂
Molecular Weight:590.951
Hs Code.:

5-benzyloxy-3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-6-(<i>tert</i>-butyl-diphenyl-silanyloxy)-hexanal

Synonyms:5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal

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Chemical Property of 5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal

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Technology Process of 5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal

There total 7 articles about 5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 913193-73-4
(4S,6R)-6-benzyloxy-4-(tert-butyldimethylsilanyloxy)-7-(tert-butyldiphenylsilanyloxy)hept-1-ene

: 913193-93-8
5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal

Guidance literature:: (4S,6R)-6-benzyloxy-4-(tert-butyldimethylsilanyloxy)-7-(tert-butyldiphenylsilanyloxy)hept-1-ene; With pyridine; ozone; In methanol; dichloromethane; at -78 ℃; for 0.75h;

With dimethylsulfide; In methanol; dichloromethane; at -78 - 20 ℃; for 12h;
DOI:10.1021/jo0610412

Reference yield:

: 913193-72-3
(3R)-3-benzyloxy-4-(tert-butyldiphenylsilanyloxy)butyraldehyde

: 913193-93-8
5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal

Guidance literature:: Multi-step reaction with 3 steps

1.1: 80 percent / TiCl₄ / CH₂Cl₂ / 0.33 h / -78 °C

2.1: 97 percent / 2,6-lutidine / CH₂Cl₂ / 2 h / 0 °C

3.1: O₃; pyridine / methanol; CH₂Cl₂ / 0.75 h / -78 °C

3.2: 99 percent / Me₂S / methanol; CH₂Cl₂ / 12 h / -78 - 20 °C

With pyridine; 2,6-dimethylpyridine; titanium tetrachloride; ozone; In methanol; dichloromethane;
DOI:10.1021/jo0610412

Reference yield:

: (6R)-6-benzyloxy-7-(tert-butyldiphenylsilanyloxy)hept-1-en-4-ol

: 913193-93-8
5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-hexanal

Guidance literature:: Multi-step reaction with 2 steps

1.1: 97 percent / 2,6-lutidine / CH₂Cl₂ / 2 h / 0 °C

2.1: O₃; pyridine / methanol; CH₂Cl₂ / 0.75 h / -78 °C

2.2: 99 percent / Me₂S / methanol; CH₂Cl₂ / 12 h / -78 - 20 °C

With pyridine; 2,6-dimethylpyridine; ozone; In methanol; dichloromethane;
DOI:10.1021/jo0610412